폐윤활유를 이용한 아스팔트 실란트

Asphalt Sealant Containing the Waste Lubricant Oil

  • 김석준 (군산대학교 공과대학 나노화학공학과) ;
  • 고금진 (군산대학교 공과대학 나노화학공학과)
  • Kim, Seog-Jun (Department of Nano and Chemical Engineering, Kunsan National University) ;
  • Ko, Kum-Jin (Department of Nano and Chemical Engineering, Kunsan National University)
  • 발행 : 2009.03.30

초록

본 연구에서는 폐윤활유를 이용하여 아스팔트 포장도로의 균열 보수에 주로 사용하는 아스팔트 실란트를 제조하였다. 아스팔트(AP-5), SBS 삼블록 공중합체(triblock copolymer), 점착제(석유수지) 및 산화방지제를 폐윤활유와 혼합하여 콘 침입도, 연화점, 신도, 흐름성, 인장 접착 신율 및 원상회복률을 측정하였다. 폐윤활유 함량이 증가함에 따라 아스팔트 실란트의 콘 침입도는 증가하였고 연화점, 신도 및 원상회복률은 감소하였다. 증량제로 탈크를 첨가할 경우 함량에 비례하여 연화점 및 원상회복률은 증가하였으나 콘 침입도, 신도 및 인장 접착 신율은 감소하였다. 석유수지 함량을 크게 줄여 ASTM 규격에 적합하면서도 가장 경제적인 균열 보수용 아스팔트 실란트를 제조할 수 있었다.

Asphalt sealants for the crack repair of asphalt concrete road were prepared using waste lubricant oil in this work. The waste lubricant oil was compounded with asphalt(AP-5), SBS triblock copolymer, a tackifying agent(petroleum resin), and antioxidants. Cone penetration, softening point, ductility, elongation by tensile adhesion, and resilience of asphalt sealant compounds were measured. Cone penetration of asphalt sealant compounds increased with the increase of waste lubricant oil content while their softening point, ductility, and resilience decreased. By the addition of talc as an extender, softening point and resilience of asphalt sealants increased, but cone penetration, ductility, and elongation by tensile adhesion of those decreased with the proportion of talc content. The most economic asphalt sealant which could pass an ASTM specification could be manufactured by the big decrement of petroleum resin content.

키워드

참고문헌

  1. Y. Yildirim, 'Polymer Modified Asphalt Binders', Construction and Building Materials, 21, 66 (2007) https://doi.org/10.1016/j.conbuildmat.2005.07.007
  2. H. Ozen, A. Aksoy, S. Tayfur, and F. Celik, 'Laboratory Performance Comparison of the Elastomer-Modified Asphalt Mixtures', Building and Environment, 43, 1270 (2008) https://doi.org/10.1016/j.buildenv.2007.03.010
  3. C. Fang, T. Li, Z. Zhang, and X. Wang, 'Combined Modification of Asphalt by Waste PE and Rubber', Polymer Composites, 29, 1183 (2008) https://doi.org/10.1002/pc.20424
  4. B. Sengoz and G. Isikyakar, 'Evaluation of the Properties and Microstructures of SBS and EVA Polymer Modified Bitumen', Construction and Building Materials, 22, 1897 (2008) https://doi.org/10.1016/j.conbuildmat.2007.07.013
  5. G. Polacco, J. Stastna, D. Biondi, F. Antonelli, Z. Vlachovicova, and L. Zanzotto, 'Rheology of Asphalts Modified with Glycidylmethacrylate Functionalized Polymers', J. Colloid Interf. Sci., 280, 366 (2004) https://doi.org/10.1016/j.jcis.2004.08.043
  6. G.D. Airey, 'Styrene Butadiene Styrene Polymer Medication of Road Bitumens', J. Mater. Sci., 99, 951 (2004)
  7. K-H. Chung and Y-K. Hong, 'Scrap Tire/Aggregate Composite: Composition and Primary Characterization for Pavement Material', Polymer Composites, 23, 852 (2002) https://doi.org/10.1002/pc.10483
  8. M.B. Ko and Y.K. Hong, 'Improvement of Deformation Resistancy of Asphalt by Modification with Tire Rubber', Elastomer, 43, 72 (2008)
  9. Q. Wang, M. Liao, Y. Wang, and Y. Ren, 'Characterization of End-Functionalized Styrene-Butadiene-Styrene Copolymers and Their Application in Modified Asphalt', J. Appl. Polym. Sci., 103, 8 (2007) https://doi.org/10.1002/app.23867
  10. K-S. Kim and Y-K. Hong, 'A Study on the Storage Stability of Waste Vinyl-Modified Asphalt', Elastomer, 43, 191 (2008)
  11. S. Hinislioglu and E. Agar, 'Use of Waste High Density Polyethylene as Bitumen Modifier in Asphalt Concrete Mix', Materials Letters, 58, 267 (2004) https://doi.org/10.1016/S0167-577X(03)00458-0
  12. R. Siddique, J. Khatib, and I. Kaur, 'Use of Recycled Plastic in Concrete: A Review', Waste Management, 28, 1835 (2008) https://doi.org/10.1016/j.wasman.2007.09.011
  13. M. Garcia-Morales, P. Partal, F. J. Navarro, F. Martinez-Boza, C. Gallegos, N. Gonzalez, and M. E. Munoz, 'Viscous Properties and Microstructure of Recycled EVA Modified Bitumen', Fuel, 83, 31 (2004) https://doi.org/10.1016/S0016-2361(03)00217-5
  14. R.L. Cottingham, D.J. Thorpe, and E. Bickerstaff, 'Method of Sealing Bridge Deck Joints', US Patent 4324504 (1982)
  15. F.R. Davis, 'Method of Modifying Asphalt with Thermoplastic Polymers, Ground Rubber and Composition Produced', US Patent 4485201 (1984)
  16. Won-il Park, 'Asphalt Sealant Containing the Waste Yogurt Bottle', Thesis, Kunsan National University, 2005
  17. S. Kim, 'Asphalt Sealant Containing the Waste Edible Oil', Elastomer, 39, 61 (2004)
  18. S-S. Kim and J-K. Jeon, 'Pyrolysis Characteristics of Waste Ship Lubricating Oil', J. Korean. Ind. Eng. Chem., 15, 564 (2004)
  19. M.J. Fuentes, R. Font, M.F. Gomez-Rico, and I. Martin-Gullon, 'Pyrolysis and Combustion of Waste Lubricant Oil from Diesel Cars: Decomposition and Pollutants', J. Anal. Appl. Pyrolysis, 79, 215 (2007) https://doi.org/10.1016/j.jaap.2006.12.004
  20. T. Bhaskar, M.A. Uddin, A. Muto, Y. Sakata, Y. Omura, K. Kimura, and Y. Kawakami, 'Recycling of Waste Lubricant Oil into Chemical Feedstock or Fuel Oil over Supported Iron Oxide Catalysis', Fuel, 9 (2004) https://doi.org/10.1016/S0016-2361(03)00216-3
  21. R. Thavasi, S. Jayalakshmi, T. Balasubramanian, and I.M. Banat, 'Biosurfactant Production by Corynebacterium Kutscheri from Waste Motor Lubricant Oil and Peanut Oil Cake', Letters in Applied Microbiology, 45, 686 (2007) https://doi.org/10.1111/j.1472-765X.2007.02256.x
  22. R. Varma, H. Takeichi, J.E. Hall, Y.F. Ozawa, and T. Kyu, 'Miscibility Studies on Blends of Kraton Block Copolymer and Asphalt', Polymer, 43, 4667 (2002) https://doi.org/10.1016/S0032-3861(02)00303-8
  23. M. Korhonen and A. Kellomaki, 'Miscibilities of Polymers in Bitumen and Tall Oil Pitch under Different Mixing Conditions', Fuel, 75(15), 1727 (1996) https://doi.org/10.1016/S0016-2361(96)00160-3
  24. A.A. Yousefi, A. Ait-Kadi, and C. Roy, 'Effect of Used-Tire-Derived Pyrolytic Oil Residue on the Properties of Polymer-Modified Asphalts', Fuel, 79, 975 (2000) https://doi.org/10.1016/S0016-2361(99)00216-1
  25. Jehun Kim, 'Performanc Improvement of Asphalt Sealant Using LDPE', Thesis, Kunsan National University, 2001
  26. J-F. Masson, P. Collins, and M. Lowery, 'Temperature Control of Hot-Poured Sealants During the Sealing of Pavement Cracks', Construction and Building Materials, 19, 423 (2005) https://doi.org/10.1016/j.conbuildmat.2004.09.001