Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Electrochemical Properties of Langmuir-Blodgett(LB) Film of Alkyl Bromides

브롬화 알킬화합물 LB막의 전기화학적 특성

  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University) ;
  • Son, Tae-Chul (Dept. of Chemical Engineering, Changwon National University) ;
  • Min, Chang-Hun (Dept. of Chemical Engineering, Changwon National University)
  • 박근호 (창원대학교 화공시스템공학과) ;
  • 손태철 (창원대학교 화공시스템공학과) ;
  • 민창훈 (창원대학교 화공시스템공학과)
  • Published : 2009.12.31
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Abstract

We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.

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References

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