Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Rheological Behaviour of Surfactant Mixtures by Varying the Concentration of Polyols

폴리올 농도를 변화시킨 계면활성제 혼합물의 유변학적 거동

  • Cho, Wan-Goo (College of Alternative Medicine, Jeonju University) ;
  • Kim, Gee-Sun (Household & Health Care R&D Center, LG H&H Ltd)
  • 조완구 (전주대학교 대체의학대학 기초의과학과) ;
  • 김기선 (LG 생활건강기술원)
  • Published : 2009.12.31
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Abstract

We have investigated the effects of polyols and NaCl on the rheological behaviours of surfactant mixtures. Sodium lauryl ether sulfate (SLES), cocamidopropyl betaine (CAPB), disodium cocoamphodiacetate (DSCA), cocamide DEA (CDEA) and lauroyl/myristoyl DEA (LMDE) were used as surfactants. The polyols added into the surfactant mixture were 1,3-butylene glycol, propylene glycol, glycerin, sorbitol, dipropylene glycol, PEG 1500 and PEG 400. The addition of amphoteric surfactant to SLES aqueous solution lead to increase the height of foam and the viscosity of the system. The addition of nonionic surfactant, LMDE or CDEA to the SLES aqueous solution increased the viscosity and the effect of LMDE was better than that of CDEA. The effect of adding polyols and NaCl into the surfactant mixture aqueous solution lead to increase or decrease the viscosity of the systems depending on the concentration of NaCl and the kinds of polyols. These results can be explained through the salting in or salting out of surfactant of the systems.

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References

  1. W. G, Cho, K. Y. Kyung and S. M. Yu, Stability of Paeoniflorin used as Anti-wrinkle Agents in Emulsions, J. Kor. Oil Chem. Soc., 26(2), 191 (2009)
  2. K. H. Lim, Biosurfactants: Their Structures, Properties, and Applications, J. Kor. Oil Chem. Soc., 13(2), 1 (1996)
  3. J. F. Scamehorn, (Ed.), Phenomena in Mixed Surfactant Systems, ACS Symposium Series 311, American Chemical Society, Washington, DC (1986)
  4. P. M. Holland, and D. M. Rubingh, Mixed Surfactant Systems, ACS Symposium Series 501. American Chemical Society, Washington, DC (1992)
  5. A. Khan, and E. Marques, Catanionic Surfactants, In Specialist Surfactants, Robb, I.D.(Ed.), Blackies Academic and Professional, London, 37-80 (1997)
  6. M. Abe, and J. F. Scamehorn, Mixed Surfactant Systems, 2nd ed., Surfactant Science Series Vol. 124, Marcel Dekker, New York, NY (2004)
  7. K. L. Stellner, J. C. Amante, and J. H. Harwell, Precipitation Phenomenon in Mixtures of Anionic and Cationic Surfactants in Aqueous Solutions, J. Colloid Interface. Sci., 123(1), 186-200(1988) https://doi.org/10.1016/0021-9797(88)90235-4
  8. J. C. Amante, J. F. Scamehorn, and J. H. Harwell, Precipitation of Mixtures of Anionic and Cationic Surfactants, J. Colloid Interface Sci., 144(1), 243 (1991) https://doi.org/10.1016/0021-9797(91)90255-7
  9. Y. S. Kang, K. Y. Kyung. M. J. Rang, D. H. Bae, Y. G. Lee, W. G. Cho, S. G. Choi and S. G. Han, Cosmetics and Household Product Science, Shin Kwang Press, vol. 2, p. 168 (2008)
  10. T. Iwanaga, M. Suzuki and H. Kunieda, Effect of Added Salts or Polyols on the Liquid Crystalline Structures of Polyoxyethylene-type Nonionic Surfactants, Langmuir, 14, 5775 (1998) https://doi.org/10.1021/la980315g
  11. K. Aramaki, U. Olsson, Y. Yamaguchi and K. Kunieda, Effect of Water-soluble Alcohols on Surfactant Aggregation in the C1$_12$EO$_8$ System, Langmuir, 15, 6226 (1999) https://doi.org/10.1021/la9900573
  12. K. Shigeta, U. Olsson and H. Kunieda, Glycerol Effects on the Formation and Rheology of Cubic Phase and Related Gel Emulsion, Stud. Surf. Sci. Catal., 132, 93 (2001) https://doi.org/10.1016/S0167-2991(01)82042-5
  13. R. Ivanova, B. Lindman and P. Alexandridis, Effect of Pharmaceutically Acceptable Glycols on the Stability of the Liquid Crystalline Gels Formed by Poloxamer 407 in Water, J. Colloid Interface Sci., 252, 226 (2002) https://doi.org/10.1006/jcis.2002.8417
  14. American Society for Testing and Materials, Method Dl173-53, Philadelphia, (1953)
  15. T. Joshi, J. Mata and P. Bahadur, Micellization and Interaction of Anionic and Nonionic Mixed Surfactant Systems in Water, Colloids and Surfaces A: Physicochem. Eng. Aspects, 260, 209 (2005) https://doi.org/10.1016/j.colsurfa.2005.03.009
  16. D. Varade, T. Joshi, V. K. Aswal, P. S. Goyal, P. A. Hassan and P. Bahadur, Micellar Behavior of Mixtures of Sodium Dodecyl Sulfate and Dodecyldimethylamine Oxide in Aqueous Solutions, Colloids and Surfaces A: Physicochem. Eng. Aspects, 259, 103 (2005) https://doi.org/10.1016/j.colsurfa.2005.02.019
  17. A. M. Howe and A. R. Pitt, Rheology and Stability of Oil-in-water Nanoemulsions Stabilised by Anionic Surfactant and Gelatin, Adv. Colloid and Interface. Sci., 144, 24 (2008) https://doi.org/10.1016/j.cis.2008.08.003
  18. N. Bouguerraa, M. M. Jebaria, R. Gomatia and A. Gharbia, Surfactant Self-Assembly in Alcohol-rich Solutions, Physica B, 367, 124 (2005) https://doi.org/10.1016/j.physb.2005.06.006
  19. A.-L. Kjoniksen and A. Laukkane, Anomalous Turbidity, Dynamical, and Rheological Properties in Aqueous Mixtures of a Thermoresponsive PVCL-g-C11EO42 Copolymer and an Anionic Surfactant, Colloids and Surfaces A: Physicochem. Eng. Aspects, 316, 159 (2008) https://doi.org/10.1016/j.colsurfa.2007.09.002
  20. H. Kunieda, M. Tanimoto, K. Shigeta and C. Rodriguez, Highly Concentrated Cubic-Phase Emulsions: Basic Study on D-Phase Emulsification using Isotropic Gels, J. Oleo Sci., 50, 633 (2001) https://doi.org/10.5650/jos.50.633
  21. M. M. Alam, L. K. Shrestha and K. Aramaki, Glycerol Effects on the Formation and Rheology of Cubic Phase and Related Gel Emulsion, J. Colloid Interface. Sci., 329, 366 (2009) https://doi.org/10.1016/j.jcis.2008.09.074