Qualitative Properties of Wild Grape Wine having Different Aging Periods

숙성기간에 따른 머루와인의 품질적 특성

  • Kang, Byung-Tae (Dept. of Hotel Culinary Art & Baking Technology, Gimcheon College) ;
  • Yoon, Ok-Hyun (Dept. of Food & Nutrition, Gimcheon College) ;
  • Lee, Jae-Woo (Dept. of Food & Nutrition, Gimcheon College) ;
  • Kim, Soon-Hee (Dept. of Hotel Culinary Art & Baking Technology, Gimcheon College)
  • Published : 2009.12.31

Abstract

Qualitative properties- polyphenol compounds(total phenolics, anthocyanin, flavonoids, tannins), color parameters and antioxidant activities- of wild grape wine having different aging periods were studied. The contents of total phenolics and anthocyanin decreased significantly in accordance with aging terms(p<0.05). The total phenolics and anthocyanin of the oldest wine(WG3) represented only 43% and 45% of it's related compound in the wine aged for one year(WG1), respectively. The contents and the degree of polymerization of tannins, including condensed tannins, also decreased but not showed statistically significant. However, The contents of flavonoids of the 2 year old wine(WG2) decreased significantly related to that of WG1, remaining, then, almost constant at that levels during aging. The L* values, b(yellow) values and the hue (hab) values were increased in long aged wines(WG2, WG3), while the intensity of color(CI) and, the a(red) parameter value decreased. The antiradical activity of wild grape wines was shown to be high(87 EDA%) in WG1. The corresponding coefficient of tannin concentrations with antiradical activity($r^2$=0.9189) suggests that the tannin content may be strongly related to the antioxidant properties of wild grape wines.

오크통에서 숙성기간이 다른 머루와인의 페놀 화합물 함량과 색, 항산화 활성 등을 분석하였다. 페놀 화합물의 함량은 숙성기간이 긴 머루와인일수록 감소하였는데, 그 경향은 종류에 따라 차이가 있었다. 총 페놀, 안토시아닌, 탄닌은 숙성기간이 길수록 감소하였고 플라보노이드는 숙성 2년 와인에서 크게 낮았으나 그 이후에는 차이가 없었다. 특히, 총 페놀과 안토시아닌은 유의성 있는 함량 차이를 보였다. 탄닌의 중합도와 축합된 탄닌의 함량도 숙성기간에 따라 감소하는 경향을 나타내었으나 유의성은 없었다. 와인의 명도(L*)는 숙성기간이 길수록 높아져 점차 밝은 색으로 변화하였으나 색의 강도(CI)는 감소하였는데, 대조군인 포도와인의 강도보다는 높았다. 머루와인의 적색소(a)는 감소하였고, 노란색소(b)와 색상(hab)은 점차 증가하는 경향을 보였다. 숙성기간이 1년인 머루와인의 자유라디칼 포획효과가 87% 내외로 항산화제 BHA(90%)와 Quercetin(92%)만큼 높은 활성을 나타내었다. 이러한 활성은 장기 숙성와인에서도 80% 내외를 유지하였다. 페놀 화합물의 종류별 함량과 항산화 활성의 상관관계를 회기 분석한 결과, 총 페놀, 플라보노이드, 안토시아닌, 탄닌의 상관계수($r^2$)가 각각 0.7625, 0.7005, 0.1136, 0.9189로 나타났다.

Keywords

References

  1. Arnous A, Makris DP, Kefalas P. 2001. Effect of principal polyphenolic components in relation to antioxidant characteristics of aged red wines. J Agric Food Chem 49:5736-5742 https://doi.org/10.1021/jf010827s
  2. Blois MS. 1958. Antioxidant determination by the use of a stable free radical. Nature 181:1199-1200 https://doi.org/10.1038/1811199a0
  3. Boido E, Alcalde-Eon C, Carrau F, Dellacassa E, Rivas-Gonzalo C. 2006. Aging effect on the pigment composition and color of Vitis vinifera L. Cv. tannat wines. Contribution of the main pigment families to wine color. J Agric Food Chem 54:6692-6704 https://doi.org/10.1021/jf061240m
  4. Cheynier V, Duenas-Paton M, Salas E, Maury C, Souquet JM, Sami-Manchado P, Fulcrand H. 2006. Structure and properties of wine pigments and tannins. Am J Enol Vitic 57:298-305
  5. Choi SY, Cho HS, Kim HJ, Ryu CH, Lee JO, Sung NJ. 2006. Physiochemical analysis and antioxidative effects of wild grape(Vitis coignetiea) juice and its wine. Korean J Food & Nutr 19:311-317
  6. Drinkine J, Lopes P, Kennedy JA, Teissedre P, Saucier C. 2007. Ethylidene-bridged flavan-3-ols in red wine and correlation with wine age. J Agri Food Chem 55:6292-6299 https://doi.org/10.1021/jf070038w
  7. Girard B, Mazza G. 1998. Functional grape and citrus products. In Functional Foods: Biochemical and Processing Aspects. pp139-191. Technomic Publishing Co. Inc. Lancaster. PA
  8. Glories Y. 1978. Recherches sur la matiere colorante des vins rouges. These de doctorates sciences, Universite de bordeaux II. France
  9. He J, Santos-Buelga C, Silva AM, Mateus N, de Freitas V. 2006. Isolation and structural characterization of new anthocyaninderived yellow pigments in aged red wine. J Agric Food Chem 54:9598-9603 https://doi.org/10.1021/jf062325q
  10. Hwang JK, Ahn SY. 1975. Studies on the anthocyanins in wild vines. J Korean Agric Chem Soc 18:183-193
  11. Jiangsu New Medical College. 1977. Dictionary of Chinese Traditional Medicine(Vol 2). pp2315 Shanghai
  12. Kim SK. 1996. Deacidification of new wild grape wine. Korean J Food & Nutr 9:265-270
  13. Kim SK. 2008. Optimal condition for deacidification fermentation of wild grape wine by mixed culture. J Korean Soc Appl Biol Chem 51:17-23
  14. Markakis P. 1982. Stability of anthocyanins in foods. In Anthocyanins as Food Colors. pp163-180. Academic Press Inc. London. UK
  15. Mazza G, Miniati E. 1993. In Anthocyanins in Fruits, Vegetables and Grains. pp149-199. CRC Press. Boca Raton
  16. Miller GL. 1959. Use of dinitrosalicylic acid reagent for determination of reducing sugar. Anal Chem 31:426-428 https://doi.org/10.1021/ac60147a030
  17. National Tax Service Technical Insititute. 1999. Alcoholic Beverage Analysis rule. pp.196-197. Sejung Pub. Co. Seoul. Korea
  18. Ribereau-Gayon P, Glories Y, Maujean A, Dubourdieu D. 2000. Handbook of Enology(2nd) Vol.2. pp.177. John Wiley & Sons Ltd. England
  19. Ribereau-Gayon P, Stonestreet E. 1965. Determination of anthocyanins in red wine. Bull Soc Chim 9:2649-2652
  20. Ribereau-Gayon P, Stonestreet E. 1966. Dosage des tanins du vin rouge et determination de leur structure. Chim Anal 48:188-196
  21. Santos-Buelga C, Scalbert A. 2000. Proanthocyanidins and tanninlike compounds-Nature, occurrence, dietary intake and effects on nutrition and health. J Sci Food Agric 80:1094-1117 https://doi.org/10.1002/(SICI)1097-0010(20000515)80:7<1094::AID-JSFA569>3.0.CO;2-1
  22. Simonetti P, Pietta P, Testolin G. 1997. Polyphenol content and total antioxidant potential of selected Italian wines. J Agric Food Chem 45:1152-1155 https://doi.org/10.1021/jf960705d
  23. Singleton V, Rossi JA Jr. 1965. Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagents. Am J Enol Vitic 16:144-158
  24. Soleas GJ, Tomlinson G, Diamandis EP, Goldberg DM. 1997. Relative contributions of polyphenolic constituents to the antioxidant status of wines: Development of a predictive model. J Agric Food Chem 45:3995-4003 https://doi.org/10.1021/jf9702959
  25. Vidal S, Francis L, Noble A, Kwiatkowski M, Cheynier V. 2004. Taste and mouth-feel properties of different types of tanninlike polyphenolic compounds and anthocyanins in wine. Anal Chim Acta 513:57-65 https://doi.org/10.1016/j.aca.2003.10.017
  26. Zhishen J, Mengcheng T, Jianming W. 1999. The determiation of flavonoid contents in mulberry and their scavenging effects on superoxide radicals. Food Chem 64:555-559 https://doi.org/10.1016/S0308-8146(98)00102-2
  27. 윤옥현, 강병태, 이재우, 한만덕, 최영훈. 2005. 자두주 생성균 주 사카로마이세스속 케이씨에스 7 및 이를 이용한 자두주의 제조방법. 특허 제0483228호