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Microstructure and Electrical Properties of Poly-N-isopropylacrylamide- N-vinylcarbazole Copolymers

  • Pierson, R. (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Basavaraja, C. (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Kim, Na-Ri (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Jo, Eun-Ae (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Huh, Do-Sung (Department of Chemistry and Institute of Basic Science, Inje University)
  • Published : 2009.09.20

Abstract

Conducting poly-N-isopropylacrylamide-N-vinyl carbazole (PNI-nvc) copolymers were synthesized via in situ deposition technique by dissolving different weight percentages of N-vinyl carbazole (10, 20, 30, and 40%). The structural morphology and FT-IR studies support the interaction between PNI and N-vinyl carbazole. The temperaturedependent DC conductivity of PNI-nvc was studied within the range of 300 ${\leq}\;T\;{\leq}$ 500 K, presenting evidence for the transport properties of PNI-nvc. The DC conductivity of PNI-nvc copolymers signifies the future development of new nanocopolymers that acts as a multifunctional material.

Keywords

References

  1. Zhang, J.; Nicholas A. P. Macromolecules 2000, 33, 102 https://doi.org/10.1021/ma991398q
  2. Morisihima, Y. Prog. Polym. Sci. 1990, 25, 949
  3. Morisihima, Y. Adv. Polym. Sci. 1992, 5, 104
  4. Novakowska, M.; White, B.; Guillet, J. E. Macromolecules 1989, 22, 3903 https://doi.org/10.1021/ma00200a016
  5. Handbook of Organic Conductive Molecules and Polymer; Nalwa, H. S., Ed.; Wiley: New York, 1997
  6. MacDiarmid, A.; Kaner, R. T. Handbook of Conducting Polymers; Skotheim, Ed.; Marcel Decker: New York, 1986; p 689
  7. Fitzer, E.; Jager, H. Z. Werkstofftechn 1985, 16, 215 https://doi.org/10.1002/mawe.19850160606
  8. Yuan, L.J.; Shyu, S. S.; Lai, J. Y. J. Appl. Polym. Sci. 1991, 42, 2525 https://doi.org/10.1002/app.1991.070420918
  9. Bismarck, A.; Kumru, M. E.; Song, B.; Springer, J.; Moos, E.; Karger-kocsis, J. J. Composites A 1999, 30, 1351 https://doi.org/10.1016/S1359-835X(99)00048-2
  10. Yavuz, O.; Berlouis, L. E. A.; Hitchmann, M. L.; Saraç, A. S. Synth. Met. 2000, 110, 165 https://doi.org/10.1016/S0379-6779(99)00296-9
  11. Sarac, A. S.; Bardavit, Y. Progess in Organics 2005, 49, 85
  12. Ling, Q. D.; Cai, Q. J.; Kang, E. T.; Neoh, K. G.; Zhu, F. R.; Huang, W. J. Mater. Chem. 2004, 14, 2741 https://doi.org/10.1039/b405873a
  13. Basavaraja, C.; Pierson, R.; Vishnuvardhan, T. K.; Huh, D. S. Eur. Poly. J. 2008, 47, 1556
  14. Basavaraja, C.; Pierson, R.; Kim, J. H.; Huh, D. S. Bull. Korean Chem. Soc. 2008, 29(9), 1699 https://doi.org/10.5012/bkcs.2008.29.9.1699
  15. Basavaraja, C.; Veeranagouda, Y.; Lee, K.; Pierson, R. Huh, D. S. J. Polym. Sci. Part B: Poly. Phys. 2009, 47, 36 https://doi.org/10.1002/polb.21611
  16. Basavaraja, C.; Veeranagouda, Y.; Lee. K.; Pierson, R.; Revanasiddappa, M.; Huh, D. S. Bull. Korean Chem. Soc. 2008, 29(12), 2423 https://doi.org/10.5012/bkcs.2008.29.12.2423

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