Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Ammonium Metavanadate: A Mild and Efficient Catalyst for the Synthesis of Coumarins

  • Mandhane, Priyanka G. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Joshi, Ratnadeep S. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Ghawalkar, Anant R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Jadhav, Ganesh R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Gill, Charansingh H. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
  • Published : 2009.12.20
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Abstract

A mild and efficient method has been developed for condensation of substituted phenol with ${\beta}$-ketoester in the presence of catalytic amount of ammonium metavanadate (10 mol%) at ambient temperature to afford the corresponding substituted 4-methyl-2H-chromen-2-one in high yields under mild conditions. Utilization of commercially available inexpensive catalyst makes this manipulation very interesting from an economic perspective.

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References

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