Bulletin of the Korean Chemical Society

  • 제30권10호
  • /
  • Pages.2259-2264
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  • 2009
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Non-isothermal Decomposition Kinetics of a New High-energy Organic Potassium Salt: K(DNDZ)

  • Xu, Kangzhen (Department of Chemical Engineering, Northwest University) ;
  • Zhao, Fengqi (Xi’an Modern Chemistry Research Institute) ;
  • Song, Jirong (Conservation Technology Department, the Palace Museum) ;
  • Ren, Xiaolei (Department of Chemical Engineering, Northwest University) ;
  • Gao, Hongxu (Xi’an Modern Chemistry Research Institute) ;
  • Xu, Siyu (Xi’an Modern Chemistry Research Institute) ;
  • Hu, Rongzu (Xi’an Modern Chemistry Research Institute)
  • 발행 : 2009.10.20
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초록

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

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참고문헌

  1. Latypov, N. V.; Bergman, J.; Langlet, A.; Wellmar, U.; Bemm, U. Tetrahedron 1998, 54, 11525. https://doi.org/10.1016/S0040-4020(98)00673-5
  2. Gindulyte, A.; Massa, L.; Huang, L.; Karle, J. J. Phys. Chem. A 1999, 103, 11045. https://doi.org/10.1021/jp991794a
  3. Sorescu, D. C.; Boatz, J. A.; Thopmson, D. L. J. Phys. Chem. A 2001, 105, 5010. https://doi.org/10.1021/jp010289m
  4. Ji, G. F.; Xiao, H. M.; Dong, H. S.; Gong, X. D.; Li, J. S.; Wang, Z. Y. Acta Chim. Sinica 2001, 59, 39.
  5. Bellamy, A. J.; Goede, P.; Sandberg, C.; Latypov, N. V. The Proceedings of the 33th International Annual Conference ICT, Karlsruke, Germany, 2002.
  6. Sorescu, D. C.; Boatz, J. A.; Thompson, D. L. J. Phys. Chem. B 2003, 107, 8953. https://doi.org/10.1021/jp030258m
  7. Cai, H. Q.; Shu, Y. J.; Yu, W. F.; Li, J. S.; Cheng, B. B. Acta Chim. Sinica 2004, 62, 295.
  8. Gao, H. X.; Zhao, F. Q.; Hu, R. Z.; Pan, Q.; Wang, B. Z.; Yang, X. W.; Gao, Y.; Gao, S. L.; Shi, Q. Z. Chin. J. Chem. 2006, 24, 177. https://doi.org/10.1002/cjoc.200690034
  9. Hervé, G.; Jacob, G.; Latypov, N. Tetrahedron 2005, 61, 6743. https://doi.org/10.1016/j.tet.2005.05.010
  10. Anniyappan, M.; Talawar, M. B.; Gore, G. M.; Venugopalan, S.; Gandhe, B. R. J. Hazard. Mater. 2006, 137, 812. https://doi.org/10.1016/j.jhazmat.2006.03.034
  11. Trzciński, W. A.; Cudzilo, S.; Chylek, Z.; Szymańczyk, L. J. Hazard Mater. 2008, 157, 605. https://doi.org/10.1016/j.jhazmat.2008.01.026
  12. Zerilli, F. J.; Kuklja, M. M. J. Phys. Chem. A 2007, 111, 1721. https://doi.org/10.1021/jp067709y
  13. Herve, G.; Jacob, G.; Latypov, N. Tetrahedron 2007, 63, 953. https://doi.org/10.1016/j.tet.2006.11.031
  14. Majano, G.; Mintova, S.; Bein, T.; Klapötke, T. M. J. Phys. Chem. C 2007, 111, 6694. https://doi.org/10.1021/jp068863n
  15. Latypov, N. V.; Johansson, M.; Holmgren, E.; Sizova, E. V.; Sizov, V. V.; Bellamy, A. J. Org. Process Res. Dev. 2007, 11, 56. https://doi.org/10.1021/op068010t
  16. Fan, X. Z.; Li, J. Z.; Liu, Z. R. J. Phys. Chem. A 2007, 111, 13291. https://doi.org/10.1021/jp075889l
  17. Buszewski, B.; Michel, M.; Cudzilo, S.; Chylek, Z. J. Hazard Mater. 2009, 164, 1051. https://doi.org/10.1016/j.jhazmat.2008.09.018
  18. Rajappa, S. Tetrahedron 1981, 37, 1453. https://doi.org/10.1016/S0040-4020(01)92085-X
  19. Xu, K. Z.; Song, J. R.; Yang, X.; Chang,C. R.; Yang, X. K.; Ma, H. X.; Huang, J.; Zhao, F. Q. J. Mole. Stru. 2008, 891, 340. https://doi.org/10.1016/j.molstruc.2008.04.004
  20. Chang, C. R.; Xu, K. Z.; Song, J. R.; Yan, B.; Ma, H. X.; Gao, H. X.; Zhao, F. Q. Acta Chim. Sinica 2008, 66, 1399.
  21. Xu, K. Z.; Chang, C. R.; Song, J. R.; Zhao, F. Q.; Ma, H. X.; Lv, X. Q.; Hu, R. Z. Chin. J. Chem. 2008, 26, 495. https://doi.org/10.1002/cjoc.200890093
  22. Xu, K. Z.; Song, J. R.; Zhao, F. Q.; Heng, S. Y.; Ding, L.; Wang, Y. Y.; Hu, R. Z. J. Chin. Chem. Soc. 2009, 56, 524.
  23. Kissinger, H. E. Anal. Chem. 1957, 29, 1702 https://doi.org/10.1021/ac60131a045
  24. Ozawa, T. Bull. Chem. Soc. Jpn. 1965, 38, 1881. https://doi.org/10.1246/bcsj.38.1881
  25. Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Shi, Q. Z.; Zhang, T. L.; Zhang, J. J. Thermal Analysis Kinetics ($2^{th}^$); Science Press: Beijing, 2008.
  26. Caot, A. W.; Redfern, J. P. Nature 1964, 201(4914), 68. https://doi.org/10.1038/201068a0
  27. Hu, R. Z.; Yang, Z. Q.; Ling, Y. J. Thermochim. Acta 1988, 123, 135. https://doi.org/10.1016/0040-6031(88)80017-0
  28. MacCallum, J. R.; Tanner, J. Eur. Ploymer J. 1968, 4, 333. https://doi.org/10.1016/0014-3057(68)90021-9
  29. Satava, F.; Sestak, J. J. Therm. Anal. 1975, 8, 477. https://doi.org/10.1007/BF01910127
  30. Agrawal, R. K. J. Therm. Anal. 1987, 32, 149. https://doi.org/10.1007/BF01914557
  31. Zhang, T. L.; Hu, R. Z.; Xie, Y.; Li, F. P. Thermochim. Acta 1994, 244, 171. https://doi.org/10.1016/0040-6031(94)80216-5
  32. Smith, L. C. Thermochim. Acta 1975, 13, 1. https://doi.org/10.1016/0040-6031(75)80060-8
  33. Xu, K. Z.; Song, J. R.; Zhao, F. Q.; Cao, Z. H.; Ma, H. X.; Hu, R. Z.; Gao, H. X.; Huang, J. Acta Chim. Sinica 2007, 65, 2827.
  34. Xu, K. Z.; Song, J. R.; Zhao, F. Q.; Ma, H. X.; Gao, H. X.; Chang, C. R.; Ren, Y. H.; Hu, R. Z. J. Hazard Mater. 2008, 158, 333. https://doi.org/10.1016/j.jhazmat.2008.01.077
  35. Xu, K. Z.; Zhao, F. Q.; Song, J. R.; Chang, C. R.; Li, M.; Wang, Y. Y.; Hu, R. Z. Chin. J. Chem. 2009, 27, 665. https://doi.org/10.1002/cjoc.200990109

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