Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Non-isothermal Decomposition Kinetics of a New High-energy Organic Potassium Salt: K(DNDZ)

  • Xu, Kangzhen (Department of Chemical Engineering, Northwest University) ;
  • Zhao, Fengqi (Xi’an Modern Chemistry Research Institute) ;
  • Song, Jirong (Conservation Technology Department, the Palace Museum) ;
  • Ren, Xiaolei (Department of Chemical Engineering, Northwest University) ;
  • Gao, Hongxu (Xi’an Modern Chemistry Research Institute) ;
  • Xu, Siyu (Xi’an Modern Chemistry Research Institute) ;
  • Hu, Rongzu (Xi’an Modern Chemistry Research Institute)
  • Published : 2009.10.20
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Abstract

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

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References

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