Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Facile Preparation of Silver Nanocolloids by Hydrogen Reduction of a Silver Alkylcarbamate Complex

  • Hong, Hyun-Ki (Department of Nanobiomedical Science, Dankook University) ;
  • Gong, Myoung-Seon (Department of Nanobiomedical Science, Dankook University) ;
  • Park, Chan-Kyo (Department of Applied Chemical Engineering, Dankook University)
  • Published : 2009.11.20
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Abstract

Controlled reduction of silver alkylcarbamate complexes with hydrogen gas was investigated as a facile synthetic method for high concentrations of silver nanocolloids in organic solvent. Polyvinylpyrrolidone (PVP) was used to stabilize the silver colloids obtained from the chemical reduction. To determine optimum conditions for preparation of the stable and controlled silver colloids with the narrowest particle size and distribution, a large number of experiments were carried out involving variations in the concentrations of the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, and 2-propanol. The initial colloid had a mean particle diameter between 5$\sim$50 nm, as measured by transmission electron microscopy, and exhibited a sharp absorption band in the UV region with a maximum size near 420 nm. After treatment with a reducing agent, the colloids were characterized by ultraviolet-visible spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy.

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References

  1. Rodr$\'{i}$iguez-S$\'{a}$nchez, L.; Blanco, M. C.; L$\'{o}$pez-Quintela, M. A. J. Phys. Chem. B 2000, 104, 9683 https://doi.org/10.1021/jp001761r
  2. Mukherjee, P.; Ahmad, A.; Mandal, D.; Senapati, S.; Sainkar, S. R.; Khan, M. I.; Parishcha, R.; Ajaykumar, P. V.; Alam, M.; Kumar, R.; Sastry, M. Nano Lett. 2001, 1, 515 https://doi.org/10.1021/nl0155274
  3. Hayashi, T.; Ohno, T.; Yatsuya, S.; Uyeda, R. Jpn. J. Appl. Phys. 977, 16, 705
  4. Mafune, F.; Kohno, J.; Takeda, Y.; Kondow, T. J. Phys. Chem. B 2000, 104, 8333 https://doi.org/10.1021/jp001803b
  5. Abid, J. P.; Wark, A. W.; Brevet, P. F.; Girault, H. H. Chem. Commun. 2002, 792
  6. Brugger, P. A.; Guendet, P.; Gratzel, M. J. Am. Chem. Soc. 1981, 103, 2923 https://doi.org/10.1021/ja00401a002
  7. Pol, V. G.; Srivastava, D. N.; Palchik, O.; Palchik, V.; Slifkin, M. A.; Weiss, A. M.; Gedanken, A. Langmuir 2002, 18, 3352 https://doi.org/10.1021/la0155552
  8. Dai, J.; Bruening, M. L.; Nano Lett. 2002, 2, 497 https://doi.org/10.1021/nl025547l
  9. Manna, A.; Imae, T.; Iida, M.; Hisamatsu, N. Langmuir 2001, 17, 6000 https://doi.org/10.1021/la010389j
  10. Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. J. Chem. Soc. Chem. Commun. 1994, 801
  11. Lee, P. C.; Meisel, D. J. Phys. Chem. 1982, 86, 3391 https://doi.org/10.1021/j100214a025
  12. Creighton, J. A.; Blatchford, C. G.; Albrecht, M. G. J. Chem. Soc. Faraday Trans. 1979, 275, 790
  13. Turkevich, J.; Stevenson, P. C.; Hiller, J. Discuss. Faraday Soc. 1951, 11, 55-75 https://doi.org/10.1039/df9511100055
  14. Evanoff, Jr., D. D.; Chumanov, G. J. Phys. Chem. B 2004, 108, 13948 https://doi.org/10.1021/jp047565s
  15. Sondi, I.; Matijevi$\'{c}$, D. V. E. J. Colloid Interface Sci. 2003, 260, 75 https://doi.org/10.1016/S0021-9797(02)00205-9
  16. Velikov, K. P.; Zegeres, G. E.; van Blaaderen, A. Langmuir 2003, 19, 1384 https://doi.org/10.1021/la026610p
  17. Rodr$\'{i}$guez-Gattorno, G.; D$\'{i}$az, D.; Rendo$\'{n}$, L.; Hern$\'{a}$ndez-Segura, G. O. J. Phys. Chem. B 2002, 106, 2482 https://doi.org/10.1021/jp012670c
  18. Nickel, U.; Castell, A.; P$\ddot{o}$ppl, K.; Shirtcliffe, N. Langmuir 2000, 16, 9087 https://doi.org/10.1021/la000536y
  19. Leopold, N.; Lendl, B. J. Phys. Chem. B 2003, 107, 5723 https://doi.org/10.1021/jp027460u
  20. Tan, Y.; Dai, X.; Li, Y.; Zhu, D. J. Mater. Chem. 2003, 13, 1069 https://doi.org/10.1039/b211386d
  21. He, R.; Qian, X.; Yin, J.; Zhu, Z. J. Mater. Chem. 2002, 12, 3783 https://doi.org/10.1039/b205214h
  22. Chen, D. H.; Huang, Y. W. J. Colloid Interface Sci. 2002, 255, 299 https://doi.org/10.1006/jcis.2002.8674
  23. Nie, S.; Emory, S. R. Science 1997, 275, 1102 https://doi.org/10.1126/science.275.5303.1102
  24. Shirtcliffe, N.; Nickel, U.; Schneider, S. J. Colloid Interface Sci. 1999, 211, 122 https://doi.org/10.1006/jcis.1998.5980
  25. Van Hyning, D. L.; Zukoski, C. F. Langmuir 1998, 14, 7034 https://doi.org/10.1021/la980325h
  26. Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169 https://doi.org/10.1016/j.jcis.2006.03.041
  27. Szyma$\'{n}$ska, I.; Piszczek, P.; Szczesny, R.; Szlyk, E. Polyhedron 2007, 26, 2440 https://doi.org/10.1016/j.poly.2006.12.028
  28. Liu, X.; Luc, S.; Zhang, J.; Cao, W. Thermochimica Acta 2006, 440, 1 https://doi.org/10.1016/j.tca.2005.08.030
  29. Monti, O. L. A.; Fourkas, J. T.; Nesbitt, D. J. J. Phys. Chem. B 2004, 108, 1604 https://doi.org/10.1021/jp030492c
  30. Singh, N.; Khanna, P. K. Mater. Chem. Phys. 2007, 104, 367 https://doi.org/10.1016/j.matchemphys.2007.03.026
  31. Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. Macromol. Res. 2008, 16, 308 https://doi.org/10.1007/BF03218522
  32. Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. Sens. Actuators B 2008, 133, 166 https://doi.org/10.1016/j.snb.2008.02.008
  33. Grodzicki, A.; Lakomska, I.; Piszczek, P.; Szyma$\'{n}$ska, I.; Szlyk, E. Coord. Chem. Rev. 2005, 249, 2232 https://doi.org/10.1016/j.ccr.2005.05.026
  34. Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. J. Colloid Interface Sci. 2008, 321, 60 https://doi.org/10.1016/j.jcis.2008.01.053
  35. Jeon, Y. M.; Cho, H. N.; Gong, M. S. Macromol. Res. 2009, 17, 2 https://doi.org/10.1007/BF03218592
  36. Lim, T. H.; Jeon, Y. M.; Gong, M. S. Polymer(Korea) 2009, 33, 33

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