Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Polymer Supported Cyanide as an Efficient Catalyst in Benzoin Condensation: An Efficient Route to α-Hydroxy Carbonyl Compounds

  • Kiasat, Ali Reza (Chemistry Department, Faculty of Sciences, Shahid Chamran University) ;
  • Badri, Rashid (Chemistry Department, Faculty of Sciences, Shahid Chamran University) ;
  • Sayyahi, Soheil (Chemistry Department, Faculty of Sciences, Shahid Chamran University)
  • Published : 2009.05.20
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Abstract

Aromatic aldehydes are efficiently self-condensed into $\alpha$-hydroxy carbonyl compounds by polystyrene-supported ammonium cyanide as an excellent organocatalyst in C-C bond formation. The reaction proceeds in water under mild reaction conditions. The polymeric catalyst can be easily separated by filtration and reused several times without appreciable loss of activity.

Keywords

References

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  2. ChemInform Abstract: Polymer-Supported Cyanide as an Efficient Catalyst in Benzoin Condensation: An Efficient Route to α-Hydroxy Carbonyl Compounds. vol.40, pp.39, 2009, https://doi.org/10.1002/chin.200939081
  3. Cyanide Anions as Nucleophilic Catalysts in Organic Synthesis vol.53, pp.19, 2009, https://doi.org/10.1055/a-1499-8943