Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Alum Catalyzed Convenient Synthesis of Quino[2,3-b][1,5 benzoxazepine α-Aminophosphonate Derivatives

  • Sonar, Swapnil S. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Sadaphal, Sandip A. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Shitole, Nana V. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Jogdand, Nivrutti R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University) ;
  • Shingate, Bapurao B. (National Chemical Laboratory) ;
  • Shingare, Murlidhar S. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
  • Published : 2009.08.20
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Abstract

We have described an efficient synthesis of quino[2,3-b][1,5]benzoxazepine α-aminophosphonate derivatives by the nucleophilic addition of triethyl phosphite to substituted quino[2,3-b][1,5]benzoxazepines promoted by easily available, inexpensive and mild catalyst KAl(S$O_4)_2{\cdot}12H_2$O(alum). The reactions proceed smoothly at room temperature under solvent-free reaction conditions and providing high yield of product in very short reaction time.

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References

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