Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Use of Correlation of 1H and 13C Chemical Shifts of N-Arylsuccinanilic Acids,N-Arylsuccinimides, N-Arylmaleanilic Acids, and N-Arylmaleimides with the Hammett Substituent Constants for the Studies of Electronic Effects

  • Lee, Hye-Sun (Department of Chemistry, Kangwon National University) ;
  • Yu, Ji-Sook (Department of Chemistry, Kangwon National University) ;
  • Lee, Chang-Kiu (Department of Chemistry, Kangwon National University)
  • Published : 2009.10.20
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Abstract

A series of N-arylsuccinanilic acids, N-arylsuccinimides, N-arylmaleanilic acids, and N-arylmaleimides was prepared and their NMR spectra were examined by correlating the $^1H\;and\;^{13}C$ chemical shift values with the corresponding Hammett $\sigma$ values. The carbonyl carbons of the amides show a normal correlation with $\sigma$ but those of the imides show an inverse correlation.

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References

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