Bulletin of the Korean Chemical Society

  • 제30권8호
  • /
  • Pages.1778-1782
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  • 2009
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis of Mesoporous TS-1 for Catalytic Oxidative Desulfurization

  • Park, Chul-Woo (Department of Chemical Engineering, Inha University) ;
  • Kim, Tae-Kyung (Department of Chemical Engineering, Inha University) ;
  • Ahn, Wha-Seung (Department of Chemical Engineering, Inha University)
  • 발행 : 2009.08.20
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초록

Mesoporous TS-1 catalysts were prepared via a nanocasting route using two different carbon template sources of CMK-3 and commercial carbon black. Products were characterized by XRD, UV-Vis spectroscopy, SEM, TEM, and $N_2$ adsorption- desorption measurement. The catalytic performances of the samples for allylchloride epoxidation and oxidative desulfurization of the representative refractory sulfur compounds, dibenzothiophene and 4,6-dimethyldibenzothiophene, were compared against those of conventional TS-1. Whilst the allychloride epoxidation activity for the mesoporus TS-1 samples were similar, mesoporous TS-1 exhibited significantly higher catalytic activities than conventional TS-1 in oxidative desulfurization.

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피인용 문헌

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  3. Preparation of tungstophosphoric acid/cerium-doped NH2-UiO-66 Z-scheme photocatalyst: a new candidate for green photo-oxidation of dibenzothiophene and quinoline using molecular oxygen as t vol.45, pp.24, 2021, https://doi.org/10.1039/d1nj00328c
  4. Synthesis of titanium silicalite‐1 with high titanium content and its catalytic performance of propylene epoxidation vol.99, pp.suppl1, 2009, https://doi.org/10.1002/cjce.23997