Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Mesoporous TS-1 for Catalytic Oxidative Desulfurization

  • Park, Chul-Woo (Department of Chemical Engineering, Inha University) ;
  • Kim, Tae-Kyung (Department of Chemical Engineering, Inha University) ;
  • Ahn, Wha-Seung (Department of Chemical Engineering, Inha University)
  • Published : 2009.08.20
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Abstract

Mesoporous TS-1 catalysts were prepared via a nanocasting route using two different carbon template sources of CMK-3 and commercial carbon black. Products were characterized by XRD, UV-Vis spectroscopy, SEM, TEM, and $N_2$ adsorption- desorption measurement. The catalytic performances of the samples for allylchloride epoxidation and oxidative desulfurization of the representative refractory sulfur compounds, dibenzothiophene and 4,6-dimethyldibenzothiophene, were compared against those of conventional TS-1. Whilst the allychloride epoxidation activity for the mesoporus TS-1 samples were similar, mesoporous TS-1 exhibited significantly higher catalytic activities than conventional TS-1 in oxidative desulfurization.

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