Inkjet Printing of Single Walled Carbon Nanotubes

  • 발행 : 2008.07.01

초록

A single-wall carbon nanotube (SWNT) transparent conductive film (TCF) was fabricated using a simple inkjet printing method. The TCF could be selectively patterned by controlling the dot size to diameters as small as $34{\mu}m$. In this repeatable and scalable process, we achieved 71% film transmittance and a resistance of 900 ohm/sq sheet with an excellent uniformity, about ${\pm}5%$ deviation overall. Inkjet printing of SWNT is substrate friendly and the TCF is printed on a flexible substrate. This method of fabrication using direct printing permits mass production of TCF in a large area process, reducing processing steps and yielding low-cost TCF fabrications on a designated area using simple printing.

키워드

참고문헌

  1. Iijima, S. and Ichihashi,T., "Single-shell carbon nanotubes of 1-nm diameter," Nature, Vol. 363, pp. 603-605, 1993 https://doi.org/10.1038/363603a0
  2. Errachid, A., Zine, N., Samitier, J. and Bausells, J., "FET-Based Chemical Sensor Systems Fabricates with Standard Technologies," Electroanalysis, Vol.16, No. 22, pp. 1843-1851, 2004 https://doi.org/10.1002/elan.200403072
  3. Zhang, Y. B., Lau, S. P., Huang, L. and Tanemura, M., "Carbon nanotubes systhesized by biased thermal chemical vapor deposition as an electron source in an x-ray tube," Appl. Phys. Lett., Vol. 86, No. 12, pp. 1231151-3, 2005
  4. Fyta, M. G. and Kelires,P. C., "Simulations of composite carbon films with nanotube inclusions," Appl. Phys. Lett., Vol. 86, No. 19, pp. 1919161-3, 2005
  5. Mu, Y., Liang, H., Hu, J. and Wan, L., "Controllable Pt Nanoparticle Deposition on Carbon Nanotubes as an Anode Catalyst for Direct Methanol Fuel Cells," J. Phys. Chem. B, Vol. 109, No. 47, 22212-6, 2005
  6. Zribi, A., Knobloch, A. and Rao, R., "CO2 detection using carbon nanotube networks and micromachined resonant transducers," Appl. Phys. Lett., Vol. 86, No. 20, pp. 2031121-3, 2005
  7. Li, C. and Chou, T. W., "Vibrational behaviors of multiwalled-carbon-nanotube-based nanomechanical resonators," Appl. Phys. Lett., Vol.84, No.1, pp. 121-3, 2004 https://doi.org/10.1063/1.1638623
  8. Hu, L., Hecht, D. S. and Gruner, G., "Percolation in Transparent and Conducting Carbon Nanotube Networks," Nano Lett., Vol. 4, No.12, pp. 2513-7, 2004 https://doi.org/10.1021/nl048435y
  9. Martin, C. A., Sandler, J. K. W., Windle, A. H., Schwarz, M.-K., Bauhofer, W.,Schulte, K. and Shaffer, M. S. P., "Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites," Polymer, Vol. 46, No.3. pp. 877-886, 2005 https://doi.org/10.1016/j.polymer.2004.11.081
  10. Wu, Z., Chen, Z., Du, X., Logan, J. M., Sippel, J., Nikolou, M., Kamaras, K., Reynolds, J. R., Tanner, D. B., Hebard, A. F. and Rinzler, A. G., "Transparent, Conductive Carbon Nanotube Films," Science, Vol. 305, No. 5688, pp. 1273-6. 2004 https://doi.org/10.1126/science.1101243
  11. Saran, N., Parikh, K., Suh, D. S., Munoz, E., Kolla, H.and Manohar, S. K., "Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates," J. Am. Chem. Soc., Vol. 126, No. 14, pp. 4462-3, 2004 https://doi.org/10.1021/ja037273p
  12. Song, Y. I., Kim, G. Y., Choi, H. K., Jeong, H. J., Kim, K. K., Yang, C. M., Lim, S. C., An, K. H., Jung, K. T. and Lee, Y. H., "Fabrication of Carbon Nanotube Field Emitters Using a Dip-Coating Method," Chem. Vap. Deposition, Vol. 12, No. 6, pp. 375-9, 2006 https://doi.org/10.1002/cvde.200506442
  13. Lee, H. J., Moon, S. I., Kim, J. K., Lee, Y. D., Nahm, S., Yoo, J. E., Han, J. H., Lee, Y. H., Hwang, S. W. and Ju, B. K. "Improvement of field emission from printed carbon nanotubes by a critical bias field," J. Appl. Phys., Vol. 98, No.1, pp. 0161071-3, 2005
  14. Bower, C., Zhou, O., Zhu, W., Ramirez, A. G., Kochanski, G. P. and Jin, S., "Fabrication and field emission properties of carbon nanotube cathodes," Mat. Res. Soc. Symp. Proc., Vol. 593, pp. 215-220, 2000
  15. Bharathan, J. and Yang, Y., "Polymer electroluminescent devices processed by inkjet printing:I. Polymer light-emitting logo," Appl. Phys. Lett., Vol. 72, No. 21, pp. 2660-2, 1998 https://doi.org/10.1063/1.121090
  16. Sele, C. W., von Werne, T., Friend, R. H.,Sirringhaus, H. "Lithography-free, Self-aligned inkjet printing with sub-hundred-nanometer resolution," Adv. Mater., Vol. 17, No. 8, pp. 997-1001, 2005 https://doi.org/10.1002/adma.200401285
  17. Kordas, K., Mustonen, T., Toth, T., Jantunen, H., Lajunen, M., Soldano, C., Talapatra, S., Kar, S., Vajtai, R. and Ajayan, P. M., "Inkjet Printing of Electrically Conductive Patterns of Carbon Nanotubes," Small, Vol. 2, No. 8-9, pp. 1021-5, 2006 https://doi.org/10.1002/smll.200600061
  18. Vivekchand S. R. C, Jayakanth R. Govindaraj A. and Rao C. N. R., "The problem of purifying single-walled carbon nanotubes," Small, Vol. 1, No. 10, pp. 1-4, 2005 https://doi.org/10.1002/smll.200590000
  19. Kaempgen M., Duesberg G.S., Roth S., "Transparent carbon nanotube coatings," Applied Surface Science, Vol. 252, No. 2, pp. 425-429, 2005 https://doi.org/10.1016/j.apsusc.2005.01.020
  20. Small, W. R., Walton, C. D., Loos, J., Panhuis, M., "Carbon Nanotube Network Formation from Evaporating Sessile Drops," J. Phys. Chem. B, Vol. 110, No. 26, pp. 13029-13036, 2006 https://doi.org/10.1021/jp062365x