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Ru-흑연 전극을 이용한 Rhodamine B의 색 제거

Decolorization of a Rhodamine B Using Ru-graphite Electrode

  • 발행 : 2008.05.30

초록

For the RhB removal from the wastewater, electrochemical method was adapted to this study. Three dimensionally stable anode (Pt, Ir and Ru) and graphite and Ru cathode were used. In order to identify decolorization, the effects of electrode, current density, electrolyte and air flow rate were investigated. The effects of electrode material, current, electrolyte concentration and air flow rate were investigated on the decolorization of RhB. Electro-Fenton's reaction was evaluated by added $Fe^{2+}$ and $H_2O_2$ generated by the graphite cathode. Performance for RhB decolorization of the four electrode systems lay in: Ru-graphite > Ru-Ru > Ir-graphite > Pt-graphite. A complete color removal was obtained for RhB (30 mg/L) at the end of 30 min of electrolysis under optimum operations of 2 g/L NaCl concentration and 2 A current. $Fe^{2+}$ addition increased initial reaction and decreased final RhB concentration. However the effect was not high.

키워드

참고문헌

  1. Kupferle M. J., 2001, Factors affecting electrolytic treatment of wastewater containing direct Red, a copper- completed azo dye, Ph. D. Dissertation, Dept. of Department of Civil and Environmental Engineering, University of Cincinnati, Cincinnati, USA
  2. Banat I. M., Nigam P., Singh D., Marchant R., 1996, Microbial decolorization of textile-dye-containing effluents: a review, Bioresource Technology, 58, 221-227
  3. Swamy J., Ramsay J. A., 1999, The evaluation of white rot fungi in the decoloration of textile dyes, Enzyme Microb. Technol., 24, 130-137 https://doi.org/10.1016/S0141-0229(98)00105-7
  4. Lin S. H., Chen M. L., 1994, Treatment of textile wastewater by chemical method for reuse, Wat. Res., 31, 868-876 https://doi.org/10.1016/S0043-1354(96)00318-1
  5. Lin S. H., Peng C. F., 1996, Treatment of textile wastewater by electrochemical method, Wat. Res., 28, 277-282
  6. Lin S. H., Peng C. F., 1996, Continuous treatment of textile wastewater by combined coagulation, electrochemical oxidation and activated sludge, Wat. Res., 30, 587-592 https://doi.org/10.1016/0043-1354(95)00210-3
  7. Rajkumar D., Kim J. G., 2006, Oxidation of various reactive dyes with in situ electro-generated active chlorine for textile dyeing industry wastewater treatment, J. of Hazardous Materials B, 136, 203-212 https://doi.org/10.1016/j.jhazmat.2005.11.096
  8. Socha A., Sochocka E., Podsiadly R., Sokolowaka J., 2007, Electrochemical and photo-electrochemical treatment of C.I. Acid Violet 1, Dyes and Pigments, 73, 390-393 https://doi.org/10.1016/j.dyepig.2006.01.007
  9. Rajeshwar K., Ibanez J. G., 1997, Environmental electrochemistry: fundamentals and applications in pollution abatement, Academic Press Inc., San Diego, CA., 1-20pp
  10. Panizza M., Barbucci A., Ricotti R., Cerisola G., 2007, Electrochemical degradation of methylene blue, Separation and Purification Technology, 54, 382-387 https://doi.org/10.1016/j.seppur.2006.10.010
  11. Vlyssides A. G., Loizidou M., Karlis P. K., Zorpas A. A., Papaioannou D., 1999, Electrochemical Oxidation of a Textile Dye Wastewater using a Pt/Ti Electrode, J. of Hazardous materials, B70, 41-52
  12. Brillas E., Cassado J., 2002, Aniline degradation by electro-Fenton and peroxi-coagulation process using a flow reactor for wastewater treatment, Chemosphere, 47, 241-248 https://doi.org/10.1016/S0045-6535(01)00221-1
  13. Chou S. S., Huang Y. H., Lee S. N., Huang G. H., Huang C. P., 1999, Treatment of high strength hexamine containing wastewater by electro-Fenton method., Wat. Res., 33, 751-759 https://doi.org/10.1016/S0043-1354(98)00276-0
  14. 권순구, 우준희, 김대수, 어수택, 정연태, 김용훈, 박춘식, 1990, 폐결핵환자에서 호중구의 $H_2O_2$ 형성 및 IgG 수용체의 표현율, 대한내과학회지, 39(5), 613-619
  15. 김동석, 박영식, 2007, 불용성 전극을 이용한 Rhodamine B의 전기화학적 탈색, 한국물환경학회지, 23(3), 377-384
  16. 김탁현, 박철환, 배우근, 신응배, 김상용, 2001, $RuO_2/Ti$ 전극에 의한 염색폐수의 전기화학적 산화 처리, 한국섬유공학회지, 38(7), 366-372
  17. Comninellis C., Nerini A., 1995, Anodic oxidation of phenol in the presence oh NaCl for wastewater treatment, J. Applied Electrochem., 25, 23-28
  18. 김운수, 차시환, 김용욱, 1993, Polyvinyl alchol 함유 폐수의 전해처리에 관한 연구, 한국물환경학회지, 9(1), 31-40
  19. 유석봉, 2005, 전기분해를 이용한 가정용정수기의 살균특성 연구, 석사학위논문, 환경공학과, 인하대 학교 석사학위논문, 인천
  20. 김동석, 박영식, 2007, 펜톤, 펜톤-유사 및 광-펜톤- 유사 반응을 이용한 Rhodamine B의 탈색, 한국환경 보건학회지, 33(2), 150-157 https://doi.org/10.5668/JEHS.2007.33.2.150
  21. 김동석, 박영식, 2007, Electro Fenton 반응을 위한 불용성 전극의 과산화수소 생성, 한국환경과학회 추계학술발표회논문집, 16(2), 425-428

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