한국염색가공학회지 (Textile Coloration and Finishing)

  • 제20권2호
  • /
  • Pages.66-74
  • /
  • 2008
  • /
  • 1229-0033(pISSN)
  • /
  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
권호 표지
DOI QR코드

DOI QR Code

분산염료 염색공정이 PET직물의 UV경화형 방염가공에 미치는 영향

Effect of Disperse Dyeing on UV-curable Flame-retardant Finish of PET Fabrics

  • 정용균 (금오공과대학교 신소재시스템공학부 나노바이오텍스타일공학과) ;
  • 장진호 (금오공과대학교 신소재시스템공학부 나노바이오텍스타일공학과)
  • Jeong, Yong-Kyun (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology)
  • 발행 : 2008.04.27
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.

키워드

참고문헌

  1. J. Jang, Y. Jeong, Nano Roughening of PET Fabrics via Continuous $UV/O_3$ Irradiation, Dyes & Pigments, 69, 137-143(2006) https://doi.org/10.1016/j.dyepig.2005.02.010
  2. J. Jang, M. Kim, and Y. Jeong, Cationic Dyeable Treatment of PET and PTT Fabrics by Continuous $UV/O_3$ Irradiation, Text. Sci. Eng., 40(5), 424-430(2003)
  3. J. Jang, S. Eom, and Y. H. Kim, Continuous Surface Modification of PET Film via Irradiation, Text. Sci. Eng., 39(1), 100-107(2002)
  4. P. K. Pak, B. O. Lee, H. C. Kim and H. Y. Kim, Flame-retardant and water-repellent finishing of automobile indoor fabrics, J. Korean Soc. Dyers & Finishers, 11(5), 285-290 (1999)
  5. E. S. Lee, K. G. Song and S. W. Ko, Thermal Behavior of Flame-retardant Polyester Fibers, Text. Sci. Eng., 28(4), 75-80(1991)
  6. H. Kubokawa. and T. Hatakeyama, Relationship Between Flame Retardation and Phase Transition Behavior of Polyester Fabrics Treated with a Bromine-Containing Compound, Textile Res. J., 68(7), 502-508(1998) https://doi.org/10.1177/004051759806800706
  7. R. Horrocks, M. Wang and M. Hall, Effectiveness of Phosphorus-Containing Flame Retardant in Textile Back-coating Formulations, J. Ind. Text., 29(3), 206-239(2000) https://doi.org/10.1106/CNKB-C14V-2EL7-H5JN
  8. H. K. Kim, J. H. Keum, H. S. Hahm, M. S. Pyoun and H. S. Park, Preparation of Phosphate Type Softening Flame Retardant for Sythetic Fibrs and its Characterization, Text. Sci. Eng., 30(10), 752-758(1993)
  9. M. J. Tsafack, J. Levalois-Grutzmacher, Flame Retardancy of Cotton Textiles by Plasmainduced Graft-polymerization(PIGP), Surf. Coat. Technol., 201, 2599-2610(2006) https://doi.org/10.1016/j.surfcoat.2006.05.002
  10. Y. J. Ju, P. K. Pak, B. O. Lee, H. C. Kim, Flame Retardant Finish of Polyester Fabrics by Corona Discharge, J. Korean Soc. Dyers & Finishers, 8(6), 65-72(1996)
  11. B. O. Lee, P. K. Pak, H. C. Kim, H. J. Lee and H. S. Lee, Multi-Functional Finish of Polyester and P/C blend Fabrics by Corona Discharge(I), J. Korean Soc. Dyers & Finishers, 9(2), 1-9(1997)
  12. J. Jang, Y. M. Kim, Y. K. Jeong and Y. S. Nam, Flame-retardant Coating of Cotton Fabrics via UV curing of DMEP, J. Korean Soc. Dyers & Finishers, 19(5), 1-7(2007)
  13. J. Jang, Y. K. Jeong, Y. J. Jeong, Peferential Face Coating of Knitted PET fabrics via UV curing for Water- and Oil-repellent Finish, J. Korean Soc. Dyers & Finishers, 17(6), 27-35(2005)