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미더덕 껍질과 PVA를 혼합한 재료로부터 제조한 복합섬유의 제법과 성질(I)

Preparation and Properties of Regenerated Composite Fibers made from Styela Clava Tunics/PVA Blending(I)

  • 정영진 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 안병재 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 김홍성 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 최해욱 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 이언필 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 이재호 (부산대학교 생명자원과학대학, 바이오소재) ;
  • 김한도 (부산대학교 공과대학, 유기소재시스템공학과) ;
  • 박수민 (부산대학교 공과대학, 유기소재시스템공학과) ;
  • 김성동 (건국대학교 공과대학 섬유공학과)
  • Jung, Young-Jin (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • An, Byung-Jae (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Kim, Hong-Sung (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Choi, Hae-Wook (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Lee, Eon-Pil (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Lee, Jae-Ho (Dept. of Biomaterials Engineering, College of Natural Resource & Life Science, Pusan National University) ;
  • Kim, Han-Do (Dept. of Organic materials system Engineering, Pusan National University) ;
  • Park, Soo-Min (Dept. of Organic materials system Engineering, Pusan National University) ;
  • Kim, Sung-Dong (Department of Textile Engineering, Konkuk University)
  • 발행 : 2008.04.27

초록

Regenerated composite fibers are prepared from solution(styela clava tunics /poly vinyl alchol) using N-methylmorpholine-N-oxide(NMMO)/water(87/13)(wt/wt) as a solvent by dry-wet spinning. The chemical cellulose (94%, ${\alpha}$-cellulose content) used for this study is extracted from styela clava tunics (SCT, Midduck), which are treated in chemical process and mechanical grinding. The structure and physical properties of regenerated composite fibers were investigated through IR-spetra, DSC, TGA and SEM. The optimal blend ratio of SCT/PVA for spinning solution was 70/30 and the total weight was 4% concentrations in NMMO/water solvent system. The fiber density, moisture contents and the degree of swelling were $1.5(g/cm^3)$ 10.2(%) and 365(%), respectively. The crystallinity index of composite fibers are decreased as the PVA contents increased. Thermal decomposition of composite fibers took place in two stages at around $250^{\circ}C$ and $550^{\circ}C$. The best thermal stability was obtained with 30% PVA contents.

키워드

참고문헌

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피인용 문헌

  1. Preparation and Characterization of Cotton Linter Based Regenerated Cellulose Fiber by Dry Jet-wet Spinning vol.50, pp.1, 2013, https://doi.org/10.12772/TSE.2013.50.025