Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
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Hard Coatings on Polycarbonate Plate Using Poly(benzoylphenylene) and Its Copolymers

폴리카보네이트 판 위에 Poly(benzoylphenylene)과 그의 공중합체들을 이용한 하드 코팅

  • Shin, Yeon-Rok (Department of Chemistry, Chungbuk National University) ;
  • Shin, Young-Jae (Department of Electrical and Computer Engineering, Texas A&M University, College Station) ;
  • Yang, Do-Hyeon (Korea Automotive Technology Institute) ;
  • Oh, Mee-Hye (Korea Automotive Technology Institute) ;
  • Yoon, Yeo-Seong (Korea Automotive Technology Institute) ;
  • Shin, Jae-Sup (Department of Chemistry, Chungbuk National University)
  • Published : 2008.09.30
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Abstract

Hard coatings were deposited on a polycarbonate plate as potential substitutes for glass in cars. In this research polyphenylene derivatives were synthesized and the coatings were conducted on a polycarbonate plate. Poly(benzoylphenylene) and its phenylene copolymers were synthesized. Using poly (benzoylphenylene), the coating showed 1H class of pencil hardness. And using its copolymers, the coating showed 2H class of pencil hardness. The copolymer also showed the better abrasion resistance than homopoly (benzoylphenylene).

자동차의 유리를 폴리카보네이트로 대체하기 위하여 폴리카보네이트 판 위에 하드 코팅을 시도하였다. 본 연구에서는 polyphenylene 유도체들을 합성하여 이것들을 이용하여 폴리카보네이트 판 위에 코팅을 시도하였다. 합성한 polyphenylene 유도체는 poly(benzoylphenylene)과 그의 phenylene 공합체들이다. Poly (benzoylphenylene)을 이용한 코팅은 최고 연필 경도 1H를 나타내었으며, 이것의 공중합체를 이용한 코팅에서는 최고 연필 경도 2H를 나타내었다. 내마모성도 공중합체가 더 우수한 결과를 보여 주었다.

Keywords

References

  1. S. R. Kim, M. K. Kang, Y. J. Shin, M. H. Oh, Y. S. Yoon, and J. S. Shin, Polymer(Korea), 31, 485 (2007)
  2. Y. J. Ji, H. Y. Kim, Y. S. Yoon, S. W. Lee, and J. S. Shin, J. Adhesion Interface, 6. 10 (2005)
  3. J. Y. Kim, Y. J. Shin, Y. R. Shin, Y. J. Ji, Y. S. Yoon, and J. S. Shin, J. Korean Ind. Eng. Chem., 17, 170 (2006)
  4. Y. J. Ji, Y. J. Shin, Y. R. Shin, J. Y. Kim, Y. S. Yoon, and J. S. Shin, J. Adhesion Interface, 7. 10 (2006)
  5. Y. T. Lee, D. S. Jeong, and H. J. Jeong, Polymer(Korea), 19, 753 (1995)
  6. S. E. Yoon, H. G. Woo, and D. P. Kim, Polymer(Korea), 24, 389 (2000)
  7. D. G. Park, Polym. Sci. Technol., 8, 268 (1997)
  8. H. S. Yang, O. H. Kwon, J. D. Lee, J. S. Rho, and Y. H. Kim, J. Korean Ind. Eng. Chem., 7, 823 (1996)
  9. H. K. Kim, J. G. Kim, J. A. Yu, and J. W. Hong, J. Korean Ind. Eng. Chem., 12, 287 (2001)
  10. T. H. Lee, E. S. Kang, and B. S. Bae, J. Sol-Gel Sci. Techonol., 27, 23 (2003) https://doi.org/10.1023/A:1022671625334
  11. Y. J. Eo, D. J. Kim, B. S. Bae, K. C. Song, T. Y. Lee, and S. W. Song, J. Sol-Gel Sci. Techonol., 13, 409 (1998) https://doi.org/10.1023/A:1008665010016
  12. D. K. Hwang, J. H. Moon, Y. G. Shul, K. T. Jung, D. H. Kim, and D. W. Lee, J. Sol-Gel Sci. Techonol., 26, 783 (2003) https://doi.org/10.1023/A:1020774927773
  13. M. S. Lee and N. J. Jo, J. Sol-Gel Sci. Techonol., 24, 175 (2002) https://doi.org/10.1023/A:1015208328256
  14. V. Chaturvedi, S. Tanaka, and K. Kaeriyama, Macromolecules, 26, 2607 (1993) https://doi.org/10.1021/ma00062a032
  15. M. Connolly, F. E. Karasz, and M. S. Trimmer, Macromolecules, 28, 1872 (1995) https://doi.org/10.1021/ma00110a022
  16. Y. H. Ha, C. E. Scott, and E. L. Thomas, Polymer, 42, 6463 (2001) https://doi.org/10.1016/S0032-3861(01)00159-8
  17. P. Kovacic and M. B. Jones, Chem. Rev., 87, 357 (1987) https://doi.org/10.1021/cr00078a005
  18. P. Kovacic and A. Kyriakis, J. Am. Chem. Soc., 85, 454 (1963) https://doi.org/10.1021/ja00887a019
  19. C. S. Marvel and G. E. Hartzell, J. Am. Chem. Soc., 81, 448 (1959) https://doi.org/10.1021/ja01511a047
  20. M. Abe and T. Yamamoto, Synthetic Metals, 156, 1118 (2006) https://doi.org/10.1016/j.synthmet.2006.07.004
  21. S. E. Morgan, R. Misra, and P. Jones, Polymer, 47, 2865 (2006) https://doi.org/10.1016/j.polymer.2006.02.025
  22. R. A. Vaia, R. Krishnamoorti, C. Benner, and M. Trimer, J. Polym. Sci. Part B: Polym. Phys., 36, 2449 (1998) https://doi.org/10.1002/(SICI)1099-0488(19980930)36:13<2449::AID-POLB19>3.0.CO;2-3
  23. R. W. Phillips, V. V. Sheares, E. T. Samulski, and J. M. DeSimone, Macromolecules, 27, 2354 (1994) https://doi.org/10.1021/ma00086a064
  24. G. P. Simon, M. S. Ardi, A. A. Goodwin, M. D. Zipper, S. R. Andrews, S. Shinton, G. Williams, M. Galop, and M. Trimmer, J. Polym. Sci. Part B: Polym. Phys., 36, 1465 (1998) https://doi.org/10.1002/(SICI)1099-0488(19980715)36:9<1465::AID-POLB5>3.0.CO;2-J
  25. Y. Wang and R. P. Quirk, Macromolecules, 28, 3495 (1995) https://doi.org/10.1021/ma00114a001
  26. D. Dean, M. Husband, and M. Trimmer, J. Polym. Sci. Part B: Polym. Phys., 70, 2971 (1998)
  27. T. Yammamoto, B. Wu, B. K. Choi, and K. Kubota, Chem. Lett., 720 (2000)
  28. T. Yammamoto, M. Abe, Y. Takahashi, K. Kawata, and K. Kubota, Polym. J., 35, 603 (2003) https://doi.org/10.1295/polymj.35.603