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Characteristic Changes of the Hydrated Sodium Silicate Depending on Heat Treatment Temperature

수화된 규산소다의 열처리 온도에 따른 물성변화

  • Kong, Yang-Pyo (Department of Materials Science and Engineering, Chungnam National University) ;
  • Cho, Ho-Yeon (Department of Materials Science and Engineering, Chungnam National University) ;
  • Suhr, Dong-Soo (Department of Materials Science and Engineering, Chungnam National University)
  • Published : 2008.03.31

Abstract

In order to fabricate porous ceramics, hydrated sodium silicate was synthesized by hydrothermal reaction using anhydrous sodium silicate. The microstructural and the structural characteristics of the expanded ceramics were observed depending on heat treatment temperature (550, 600, 650, $700^{\circ}C$) and then the effect of these characteristics on the compressive strength and the temperature gradient was investigated. As the heat treatment temperature was increased, the compressive strength was decreased from $0.717KN/cm^2\;(550^{\circ}C)\;to\;0.166KN/cm^2\;(700^{\circ}C)$. The temperature gradient was increased with increasing the experimental temperature regardless of the heat treatment temperature. The temperature gradient of the expanded ceramics which was heat treated at $650^{\circ}C\;was\;300^{\circ}C$. The bulk specific gravity, porosity, pore size, pore characteristics and wall thickness were varied depending on heat treatment temperature, and the compressive strength and the temperature gradient were governed by the complex effects of these factors.

Keywords

References

  1. Y. S. Choi and H. K. Kim, "Research of Incombustible Low Vacuum Insulating Material Using Silica Gel," Ministry of Commerce, Industry and Energy, 3-13 (2005).
  2. J. Y. Yoon, I. H. Song, D. S. Park, and H. D. Kim, "Technology Trend of Porous Material," Eng. & Mat., 15 [3] 98-108 (2003).
  3. J. Y. Yun, H. D. Kim, and C. H. Park, "Fabrication of double- layered Porous Materials(in Korean)," J. Kor. Ceram. Soc., 39 [10] 919-27 (2002). https://doi.org/10.4191/KCERS.2002.39.10.919
  4. G. Y. Jang, S. R. Kim, K. H. Lee, and J. H. Jung, "Manufacturing Method of Porous Ceramics(in Korean)," J. Kor. Ceram. Soc. Bull., 10 [2] 193-202 (1995).
  5. Y. P. Kong, S. H. Seo, J. H. Kim, and D. S. Suhr, "Characteristics of Porous Ceramics Depending on Water Content of the Water Glass and Heat Treatment Temperature(in Korean)," J. Kor. Ceram. Soc., 42 [10] 691-7 (2005) https://doi.org/10.4191/KCERS.2005.42.10.691
  6. Fujiu, "Processing and Properties of Cellular Silica Synthesized by Foaming Sol-Gels," J. Am. Ceram. Soc., 73 [1] 85-92 (1990). https://doi.org/10.1111/j.1151-2916.1990.tb05095.x
  7. J. S. Woyansky and C. E. Scott, "Processing of Porous Ceramics," J. Am. Ceram. Soc. Bull., 71 [11] 1674-80 (1992).
  8. S. M. Han, D.Y. Shin, and S. K. Kang, "Preparation for Porous Ceramics Using Low Grade Clay(in Korean)," J. Kor. Ceram. Soc., 35 [6] 575-82 (1998).
  9. J. K. Park and J. D. Lee, "Preparation of Porous Inorganic Materials by Foaming Slurry(in Korean)," J. Kor. Ceram. Soc., 35 [12] 1280-8 (1998).
  10. Y. P. Kong, H. Y. Cho, and D. S. Suhr, "Expansion Characteristics of the Hydrated Sodium Silicate(in Korean)," J. Kor. Ceram. Soc., 45 [1] 54-9 (2008). https://doi.org/10.4191/KCERS.2008.45.1.054
  11. H. N. Choi and S. H. Han, "Effects of Fabrication Variables and Microstructures on the Compressive Strength of Open Cell(in Korean)," J. Kor. Ceram. Soc., 36 [9] 954-61 (1999).
  12. E. Ryskewitsch, "Compression Strength of Porous Sintered Alumina and Zirconia," J. Am. Ceram. Soc., 36 [2] 65-8 (1953). https://doi.org/10.1111/j.1151-2916.1953.tb12837.x
  13. T. Matusinovic, J. Sipusic, and N. Vrbos, "Porosity-Strength Relation in Calcium Luminate Cement Pastes," Cement and Concrete Research, 33 1801-6 (2003). https://doi.org/10.1016/S0008-8846(03)00201-1
  14. E. M. Prshedromirskaya, Y. P. Kukota, and V. M. Sleptsov, "Strength Characteristics of Porous Materials of Refractory Compounds," Powder Metallurgy and Metal Ceramics, 5 [3] 238-41 (1966). https://doi.org/10.1007/BF00776233
  15. W. J. Kim, D. K. Kim, and J. H. Kim, "Thermal Conductivity of AlN Ceramics(in Korean)," Sci. & Tech. of Ceram. Mat., 9 [6] 621-9 (1994).
  16. S. H. Hyun, C. H. Lee, D. J. Kim, and D. J. Seong, "Mechanical Strength and Thermal Conductivity of Pure/ Opacified Silica Aerogels(in Korean)," J. Kor. Ceram. Soc., 34 [9] 969-78 (1997).
  17. J. Gross, J. Fricke, R. W. Pekala, and L. W. Hrubesh, "Elastic nonlinearity of aerogels," Phys. Rev. B, 45 [22] 12774-7 (1992). https://doi.org/10.1103/PhysRevB.45.12774
  18. A. L. Loeb, "Thermal Conductivity 8-A Theory of Thermal Conductivity of Porous Materials, Part2," J. Am. Ceram. soc., 37 [2] 96-9 (1954). https://doi.org/10.1111/j.1551-2916.1954.tb20107.x
  19. E. Schlegel and R. Boldt, "Dependence of Specific Thermal Conductivity of the Silton-therm Cellular Concrete on its Apparent Density and Pore Size," Silikaty, 31 [5] 227-36 (1987).
  20. O. J. Lee, K. H. Lee, T. J. Yim, S. Y. Kim, and K. P. Yoo, "Thermal Conductivity of Polyisocyanurate Aerogel for Vacuum Panel Insulator," Theories and Applications of Chemical Engineering, 6 [2] 4509-12 (2000).
  21. L. W. Hrubesh, and R. W. Pekala, "Thermal Properties of Organic and Inorganic Aerogels," J. Mater. Res., 9 [3] 731- 8 (1994). https://doi.org/10.1557/JMR.1994.0731
  22. P. K. Chang and J. B. Im, "Microstructural Effect Influencing the Thermal Conductivity of high-Temperature Insulation Firebricks(in Korean)," J. Kor. Ceram. Soc., 27 [6] 729-34 (1990).