DOI QR코드

DOI QR Code

A Study of the Dielectric Characteristics of the Low-k SiOCH Thin Films by Ellipsometry

Ellipsometry를 이용한 Low-k SiOCH 박막의 유전특성에 관한 연구

  • 이인환 (청주대학교 전자공학과) ;
  • 황창수 (공군사관학교 물리학과) ;
  • 김홍배 (청주대학교 전자정보공학부)
  • Published : 2008.12.01

Abstract

We studied the dielectric characteristics of low-k SiOCH thin films by Ellipsometry. The SiOCH thin films were prepared by deposition of BTMSM precursors on p-Si wafer by CCP-PECVD method. The nano-porous structural organic/inorganic hybrid-type of SiOCH thin films correlated directly to the formation of low dielectrics close to pore(k=1). The structural groups including highly dense pores in SiOCH thin films originated the anisotropic geometry type of network structure directing to complex refractive characteristics of SiOCH single layer on the p-Si wafer. The linearly polarized beam of Xe-ramp in the range from 190 nm to 2100 nm introduced to the surface of SiOCH thin film, and the reflected beam was Elliptically polarized by complex refractive coefficients of SiOCH dipole groups. The amplitude variation $\Psi$ and phase variation $\Delta$ of the relative reflective coefficients between perpendicular and parallel components to the incident plane were measured by Ellipsometry. The complex optical constants n and k as well as the dielectric constant and thickness of SiOCH thin films were driven by the measured value of $\Psi$ and $\Delta$.

Keywords

References

  1. W. W. Lee and P. S. Ho, "Low dielectric constant materials for ULSI interlayer dielectric applications", MRS Bulletin, Vol. 22, Issue 10, p. 19, 1997 https://doi.org/10.1557/S0883769400034692
  2. S. P. Muraka, "Low dielectric constant materials for interlayer dielectric applications", Solid State Technology, Vol. 39, Issue 3, p. 34, 1996
  3. C. H. Ting and T. E. Seidel, "Methods and needs for low-k material research", Mat. Res. Symp. Proc., Vol. 381, p. 3, 1995
  4. N. Vets, M. Smet, and W. Dehaen, "Synthesis and thermolysis of a Diels-Alder adduct of pentacene and thiophosgene", Tetrahedron Letters, Vol. 45, Issue 39, p. 7287, 2004 https://doi.org/10.1016/j.tetlet.2004.08.011
  5. Q. H. Li, D. Zhu, and W. Liu, "Optical properties of Al-doped ZnO thin films by Ellipsometry", Applied Surface Science, Vol. 254, p. 2922, 2008 https://doi.org/10.1016/j.apsusc.2007.09.104
  6. H. Neumann, W. Horing, and E. Reccius, "Growth and optical properties of $CuGaTe_{2}$ thin films", Thin Solid Films, Vol. 61, p. 13, 1979 https://doi.org/10.1016/0040-6090(79)90494-2
  7. Y. C. Liu, S. K. Tung, and J. H. Hsieh, "Influence of annealing on optical properties and surface structure of ZnO thin films", Journal of Crystal Growth, Vol. 287, Issue 1, p. 105, 2006 https://doi.org/10.1016/j.jcrysgro.2005.10.052
  8. Y. C. Liu, J. H. Hsieh, and S. K. Tung, "Extraction of optical constants of zinc oxide thin films by ellipsometry with various models", Thin Solid Films, Vol. 510, Issues 1-2, p. 32, 2006 https://doi.org/10.1016/j.tsf.2005.10.089
  9. T.-H. Baek, M.-S. Kim, and H. Kim, "Measurement of principal stress direction by photoelastic phase shifting method", Journal of Mechanical Science and Technology, Vol. 28, No. 12, p. 1982, 2004
  10. J.-W. Kim, C.-S. Hwang, and H.-B. Kim, "Properties of SiOCH thin film dielectric constant by BTMSM/$O^{2}$ flow rates", J. of KIEEME(in Korean), Vol. 21, No. 4, p. 362, 2008 https://doi.org/10.4313/JKEM.2008.21.4.362

Cited by

  1. A Study of Optical Characteristics Correlated with Low Dielectric Constant of SiOCH Thin Films Through Ellipsometry vol.23, pp.3, 2010, https://doi.org/10.4313/JKEM.2010.23.3.228
  2. Properties of Dielectric Constant and Bonding Mode of Annealed SiOCH Thin Film vol.22, pp.1, 2009, https://doi.org/10.4313/JKEM.2009.22.1.047