분석과학 (Analytical Science and Technology)

  • 제21권6호
  • /
  • Pages.562-568
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  • 2008
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  • 1225-0163(pISSN)
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  • 2288-8985(eISSN)
한국분석과학회 (The Korean Society of Analytical Sciences)
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X-ray crystal structure of two-dimensional bimetallic host clathrate with 2-aminoethanol, [Cd{NH2CH2CH2OH}2Ni(CN)4]·3C6H5NH2·H2O

  • Kim, Chong-Hyeak (Center for Chemical Analysis, Korea Research Institute of Chemical Technology) ;
  • Moon, Hyoung-Sil (Center for Chemical Analysis, Korea Research Institute of Chemical Technology) ;
  • Lee, Sueg-Geun (Center for Chemical Analysis, Korea Research Institute of Chemical Technology)
  • 투고 : 2008.10.09
  • 심사 : 2008.11.03
  • 발행 : 2008.12.25
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초록

A novel two-dimensional cadmium(II)-nickel(II) bimetallic host clathrate, $[Cd{NH_2CH_2CH_2OH}_2Ni(CN)_4]{\cdot}3C_6H_5NH_2{\cdot}H_2O$, 1, has been synthesized and structurally characterized by X-ray single crystallographic method. The clathrate 1 crystallizes in the monoclinic system, space group $P2_1/c$ with a = 14.370(3), b = 7.728(1), c = 28.172(4) ${\AA}$, ${\beta}=97.58(1)^{\circ}$, V = 3101.1(9) ${\AA}^3$, Z = 4. The host framework of the clathrate 1 is built of the cyanide bridges between octahedral Cd(II) atom and square planar Ni(II) atom. The octahedral Cd atoms ligated by two 2-aminoethanol molecules and four cyanide ligands bridged with square planar Ni atoms. The Ni atoms bridges to four Cd atoms via cyanides is made up of puckered quadrangles of composition $\{CdNi(CN)_2\}_2$, all edges are shared. This cyanide bridges form an infinite two-dimensional host networks stacking along b axis. 2-Aminoethanol ligands bond to Cd atom through N atom as a monodentate ligand in the axial position and four cyanides take an equatorial plane with all in trans-configurations. The aniline guest molecules and water molecules are located in between the host layer sheets, respectively.

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참고문헌

  1. A. Reichert, H. Ringsdorf, P. Schuhmacher, W. Baumeister and T. Scheybani, "Comprehensive Supramolecular Chemistry", Vol. 9, p. 313, Pergamon Press, Oxford, U.K., 1996
  2. L. Isaacs, D. N. Chin, N. Bowden, Y. Xia and G. M. Whitesides, "Supramolecular Materials and Technologies", p. 1, John Wiley & Sons, New York, U.S.A., 1999
  3. J. Y. Ying, C. P. Mehnert and M. S. Wong, Angew. Chem. Int. Ed., 38, 56(1999) https://doi.org/10.1002/(SICI)1521-3773(19990115)38:1/2<56::AID-ANIE56>3.0.CO;2-E
  4. S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 124, 2568(2002) https://doi.org/10.1021/ja0113192
  5. C. H. Kim, S. G. Lee and I. H. Suh, Acta Cryst., C55, 1238(1999)
  6. S. S. Yun, Y. P. Kim and C. H. Kim, Acta Cryst., C55, 2026(1999)
  7. H. S. Moon, C. H. Kim and S. G. Lee, Bull. Korean Chem. Soc., 21, 339(2000)
  8. H. S. Moon, C. H. Kim and S. G. Lee, Acta Cryst., C56, 425(2000)
  9. S. S. Yun, Y. P. Kim and C. H. Kim, J. Coord. Chem., 56, 363(2003) https://doi.org/10.1080/0095897031000092421
  10. S. S. Yun, H. S. Moon, C. H. Kim and S. G. Lee, J. Coord. Chem., 57, 17(2004) https://doi.org/10.1080/00958970310001641709
  11. S. S. Yun, H. S. Moon, C. H. Kim and S. G. Lee, J. Coord. Chem., 57, 321(2004) https://doi.org/10.1080/00958970410001671165
  12. T. Iwamoto, "Comprehensive Supramolecular Chemistry", Vol. 6, chap. 19, Pergamon Press, Oxford, U.K., 1996
  13. S. R. Batten and R. Robson, Angew. Chem. Int. Ed., 37, 1460(1998) https://doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
  14. T. Iwamoto, "Inclusion Compounds", vol. 1, chap. 2, Academic Press, London, U.K., 1984
  15. T. Iwamoto, "Inclusion Compounds", vol. 5, chap. 6, Oxford Univ. Press, Oxford, U.K., 1991
  16. H. J. Chen, G. Yang and X. M. Chen, Acta Cryst., C55, 2012 (1999)
  17. J. Kozisek, H. Paulus, M. Dankova and M. Hvastijova, Acta Cryst., C52, 3019(1996)
  18. A. L. Balch, B. C. Noll and N. Safari, Inorg. Chem., 32, 2901(1993) https://doi.org/10.1021/ic00065a017
  19. J. P. Costes, F. Dahan and J. P. Laurent, Inorg. Chem., 30, 1887(1991) https://doi.org/10.1021/ic00008a039
  20. J. P. Costes, J. F. Serra, F. Dahan and J. P. Laurent, Inorg. Chem., 25, 2790(1986) https://doi.org/10.1021/ic00236a027
  21. P. Bombicz, J. Madarasz, E. Forizs, and I. Foch, Polyhedron, 16, 3601(1997) https://doi.org/10.1016/S0277-5387(97)00104-6
  22. H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992) https://doi.org/10.1007/BF01045982
  23. Bruker, XSCANS Data Collection Software Package, Bruker, Karlsruhe, Germany, 1996
  24. Bruker, SHELXTL Structure Analysis Software Package, Bruker, Karlsruhe, Germany, 1998
  25. G. M. Sheldrick, Acta Cryst., A46, 467 (1990)
  26. K. Nakamoto, "Infrared and Raman Spectra of Inorganic and Coordination Compounds", Part B, John Wiley & Sons, New York, U.S.A., 1997