Technical Status of Carbon Nanotubes Composites

탄소나노튜브 복합체의 기술동향

  • Lee, Jong-Il (Daedeok Research Inst., Honam Petrochemical Corp.) ;
  • Jung, Hee-Tae (Department of Chemical & Biomolecular Engineering, KAIST)
  • 이종일 (호남석유화학(주) 대덕연구소) ;
  • 정희태 (한국과학기술원 생명화학공학과)
  • Received : 2007.10.15
  • Accepted : 2007.10.19
  • Published : 2008.02.28

Abstract

Carbon nanotubes are considered as the most ideal nano filler in the field of composites with their excellent electrical, mechanical, and thermal properties. Therefore carbon nanotubes composites are increasingly utilized in conductive materials, structural material with high strength and low weight and multifunctional material. This review article describes recent research trend of carbon nanotubes synthesis, modification, various properties of the carbon nanotubes composites and their application. Furthermore the future development direction for the commercialization of carbon nanotubes composites is proposed.

탄소나노튜브는 전기적, 기계적, 열적 특성면에서 모두 탁월한 물성을 나타냄에 따라 복합체 분야에서 가장 이상적인 나노충전재료로 여겨지고 있다. 그에 따라 탄소나노튜브 복합체는 전도성재료, 고강도 경량 특성의 구조재료, 다기능 복합재료 등의 응용에 있어서 그 활용도가 높아지고 있다. 본 총설에서는 탄소나노튜브의 제조방법, 개질, 탄소나노튜브 복합체의 다양한 특성 및 응용 분야에 대한 최근 연구 동향을 설명하고 탄소나노튜브 복합체 상업화에 있어서 앞으로 나아갈 방향에 대하여 다룬다.

Keywords

References

  1. Iijima, S., "Helical Microtubules of Graphitic Carbon," Nature, 354, 56-58(1991). https://doi.org/10.1038/354056a0
  2. Iijima, S. and Ichihashi, T., "Single-shell Carbon Nanotubes of 1-nm Diameter," Nature, 363, 603-605(1993). https://doi.org/10.1038/363603a0
  3. Dai, H., Rinzler, A. G., Nikolaev, P., Thess, A., Colbert, D. T. and Smalley, R. E., "Single-wall Nanotubes Produced by Metal-catalyzed Disproportionation of Carbon Monoxide," Chem. Phys. Lett., 260(3-4), 471-475(1996). https://doi.org/10.1016/0009-2614(96)00862-7
  4. Lee, Y. H, "The Physical Property and Application of Carbon Nanotube," Sea Mulli, 51(2), 84-144(2005).
  5. Treacy, M. M. J., Ebbesen, T. W. and Gilson, J. M., "Exceptionally High Young's Modulus Observed for Individual Carbon Nanotubes", Nature, 381, 678-680(1996). https://doi.org/10.1038/381678a0
  6. Krishnan, A., Dujardin, E., Ebbesen, T. W., Yianilos, P. N. and Treacy, M. M. J., "Measurement of the Young's Modulus of Single- shell Nanotubes using a TEM," Phys. Rev. B, 58(20), 14013- 14019(1998). https://doi.org/10.1103/PhysRevB.58.14013
  7. Wong, E. W., Sheehan, P. E. and Lieber, C. M., "Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes," Science, 277(5334), 1971-1975(1997). https://doi.org/10.1126/science.277.5334.1971
  8. Yu, M. F., Lourie, O., Dyer, M. J., Moloni, K., Kelly, T. F. and Ruoff, R. S., "Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load," Science, 287(5453), 637- 640(2000). https://doi.org/10.1126/science.287.5453.637
  9. Bethune, D. S., Klang, C. H., de Vries, M. S., Gorman, G., Savoy, R., Vazquez, J. and Beyers, R., "Cobalt-catalysed Growth of Carbon Nanotubes with Single-Atomic-Layer Walls," Nature, 363, 605-607(1993). https://doi.org/10.1038/363605a0
  10. Thess, A., Lee, R., Nikolaev, P., Dai, H., Petit, P., Robert, J., Xu, C., Lee, Y. H., Kim, S. G., Rinzler, A. G., Colbert, D. T., Scuseria, G. E., Tománek, D., Fischer, J. E. and Smalley, R. E., "Crystalline Ropes of Metallic Carbon Nanotubes," Science, 273(5274), 483-487(1996). https://doi.org/10.1126/science.273.5274.483
  11. Nikolaev, P., Bronikowski, M. J., Bradley, R. K., Rohmund, F., Colbert, D. T., Smith, K. A. and Smalley, R. E., "Gas-phase Catalytic Growth of Single-walled Carbon Nanotubes from Carbon Monoxide," Chem. Phys. Lett., 313(1-2), 91-97(1999). https://doi.org/10.1016/S0009-2614(99)01029-5
  12. Su, M., Zheng, B. and Liu, J., "A Scalable CVD Method for the Synthesis of Single-walled Carbon Nanotubes with High Catalyst Productivity," Chem. Phys. Lett., 322(5), 321-326(2000). https://doi.org/10.1016/S0009-2614(00)00422-X
  13. Wang, Y., Wei, F., Luo, G., Yu, H. and Gu, G., "The Large Scale Production of Carbon Nanotubes in a Nano-agglomerate Fluidized Bed Reactor," Chem. Phys. Lett., 364(5-6), 568-572(2002). https://doi.org/10.1016/S0009-2614(02)01384-2
  14. Haluska, M., Roth, S., Becher, M., Roth, S., Stepanek, I. and Bernier, P., "Hydrogen Storage in Mechanically Treated Single Wall Carbon Nanotubes," AIP Conf. Proc. 591, 603-608(2001).
  15. Pierard, N., Fonseca, A., Konya, Z., Willems, I., Van Tendeloo, G. and Nagy, J. B., "Production of Short Carbon Nanotubes with Open Tips by Ball Milling," Chem. Phys. Lett, 335(1-2), 1-8(2001). https://doi.org/10.1016/S0009-2614(01)00004-5
  16. Li, Y. B., Wei, B. Q., Liang, J., Yu, Q. and Wu, D. H., "Transformation of Carbon Nanotubes to Nanoparticles by Ball Milling Process," Carbon 37(3), 493-497(1999). https://doi.org/10.1016/S0008-6223(98)00218-8
  17. Hilding, J., Grulke, E. A., Zhang, Z. G. and Lockwood, F., "Dispersion of Carbon Nanotubes in Liquids," J. Dispersion Sci. Tech., 24(1), 1-41(2003). https://doi.org/10.1081/DIS-120017941
  18. Boul, P. J., Liu, J., Mickelson, E. T., Huffman, C. B., Ericson, L. M., Chiang, I. W., Smith, K. A., Colbert, D. T., Hauge, R. H., Margrave, J. L. and Smalley, R. E., "Reversible Sidewall Functionalization of Buckytubes," Chem. Phys. Lett., 310(3-4), 367-372(1999). https://doi.org/10.1016/S0009-2614(99)00713-7
  19. Liu, J., Casavant, M. J., Cox, M., Walters, D. A., Boul, P., Lu, W., Rimberg, A. J., Smith, K. A., Colbert, D. T. and Smalley, R. E., "Controlled Deposition of Individual Single-walled Carbon Nanotubes on Chemically Functionalized Templates," Chem. Phys. Lett., 303(1-2), 125-129(1999). https://doi.org/10.1016/S0009-2614(99)00209-2
  20. Ausman, K. D., Piner, R., Lourie, O. and Ruoff, R. S., Korobov, M., "Organic Solvent Dispersions of Single-Walled Carbon Nanotubes: Toward Solutions of Pristine Nanotubes," J. Phys. Chem. B., 104(38), 8911-8915(2000). https://doi.org/10.1021/jp002555m
  21. Liu, J., Rinzler, A. G., Dai, H. J., Hafner, J. H., Bradley, R. K., Boul, P. J., Lu, A., Iverson, T., Shelimov, K., Huffman, C. B., Rodriguez- Macias, F., Shon, Y. S., Lee, T. R., Colbert, D. T. and Smalley, R. E., "Fullerene Pipes", Science, 280(5367), 1253-1256(1998). https://doi.org/10.1126/science.280.5367.1253
  22. Mawhinney, D.B., Naumenko, V., Kuznetsova, A., Yates, J. T., Liu, J. and Smalley, R. E., "Infrared Spectral Evidence for the Etching of Carbon Nanotubes: Ozone Oxidation at 298 K," J. Am. Chem. Soc., 122(10), 2383-2384(2000). https://doi.org/10.1021/ja994094s
  23. Ago, H., Kugler, T., Cacialli, F., Salaneck, W. R., Shaffer, M. S. P., Windle, A. H. and Friend, R. H., "Work Functions and Surface Functional Groups of Multiwall Carbon Nanotubes," J. Phys. Chem. B., 103(38), 8116-8121(1999). https://doi.org/10.1021/jp991659y
  24. Riggs, J. E., Guo, Z., Carroll, D. L. and Sun, Y. P., "Strong Luminescence of Solubilized Carbon Nanotubes," J. Am. Chem. Soc., 122(24), 5879-5880(2000). https://doi.org/10.1021/ja9942282
  25. Georgakilas, V., Kordatos, K., Prato, M., Guldi, D. M., Holzinger, M. and Hirsch, A., "Organic Functionalization of Carbon Nanotubes," J. Am. Chem. Soc., 124(5), 760-761(2002). https://doi.org/10.1021/ja016954m
  26. Ruelle, B., Peeterbroeck, S., Gouttebaron, R., Godfroid, T., Monteverde, F., Dauchot, J. P., Alexandre, M., Hecq, M. and Dubois, P., "Functionalization of Carbon Nanotubes by Atomic Nitrogen Formed in a Microwave Plasma Ar + $N_2$ and Subsequent Poly$(\epsilon-caprolactone)$ Grafting," J. Mater. Chem., 17, 157-159(2007). https://doi.org/10.1039/b613581c
  27. O'Connell, M. J., Boul, P., Ericson, L. M., Huffman, C., Wang, Y., Haroz, E., Kuper, C., Tour, J., Ausman, K. D. and Smalley, R. E., "Reversible Water-solubilization of Single-walled Carbon Nanotubes by Polymer Wrapping," Chem. Phys. Lett., 342(3-4), 265-271 (2001). https://doi.org/10.1016/S0009-2614(01)00490-0
  28. Chen, J., Liu, H., Weimer, W. A., Halls, M. D., Waldeck, D. H. and Walker, G. C., "Noncovalent Engineering of Carbon Nanotube Surfaces by Rigid, Functional Conjugated Polymers," J. Am. Chem. Soc., 124(31), 9034-9035(2002). https://doi.org/10.1021/ja026104m
  29. Huang, Y., Li, N., Ma, Y., Du, F., Li, F., He, X., Lin, X., Gao, H., and Chen Y., "The Influence of Single-Walled Carbon Nanotube Structure on the Electromagnetic Interference Shielding Efficiency of its Epoxy Composites," Carbon, 45(8), 1614-1621(2007). https://doi.org/10.1016/j.carbon.2007.04.016
  30. Qian, D. and Dickey, E. C., "Load Transfer and Deformation Mechanisms in Carbon Nanotube-Polystyrene Composites", App. Phys. Lett., 76(20), 2868-2870(2000). https://doi.org/10.1063/1.126500
  31. http://www.zyvex.com.
  32. Jorio, A., Dresselhaus, M. S., Dresselhaus, G., "Carbon Nanotubes: Advanced Topics in the Synthesis, Structure, Properties and Applications," 1st ed., Springer(2007).
  33. McWilliams, A. and Brauer, S., "The Maturing ESD Market: Challenges and Opportunities for The Future," BCC Report, Report ID: PLS006D(2004).
  34. Schlechter, M., "Conductive Polymers," BCC Report, Report ID: PLS043A(2003).
  35. http://www.eikos.com.
  36. http://www.topnanosys.com.
  37. Callister, W. D., "Materials Science and Engineering: An Introduction," 6th ed., Wiley, New York(2003).
  38. http://www.news.com/2100-11395_3-6091347.html.
  39. http://www.mitre.org/work/tech_papers/tech_papers_05/04_0986/ 04_0986.pdf
  40. Eklund, P., Ajayan, P., Blackmon, R., Hart, A. J., Kong, J., Pradhan, B., Rao, A., Rinzler, A., "International Assessment of Research and Development of Carbon Nanotube Manufacturing and Applications," WTEC Panel Report(2007).