Bulletin of the Korean Chemical Society

  • 제29권7호
  • /
  • Pages.1369-1373
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Twist Boat Conformation of Thiane S-Oxide Both in Solid State and in Solution

  • Jeon, Dong-Ju (Center for Medicinal Chemistry, Korea Research Institute of Chemical Technology) ;
  • Kim, Ikyon (Center for Medicinal Chemistry, Korea Research Institute of Chemical Technology)
  • 발행 : 2008.07.20
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초록

A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.

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참고문헌

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