Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Syntheses and Structures of Two Reduced Open-framework Titanophosphates

  • Zhao, Yongnan (Institute of Nanostructured Materials, College of Materials Science and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Yu, Jianguo (Institute of Nanostructured Materials, College of Materials Science and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Kwon, Young-Uk (Department of Chemistry & BK21 School of Chemical Materials Science, Sungkyunkwan University)
  • Published : 2008.04.20
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Abstract

Using metallic Ti powder as raw materials and 1,2-diaminocyclohexane (DACH) as the trial template, two novel reduced titanophosphate open-structures were hydrothermally isolated by varying the $H_3PO_4/H_2O$ ratio to adjust the pH value. TiPO-1 crystallizes in orthorhombic Pbca space group with cell parameters a = 21.956(3) $\AA$, b = 8.6268(11) $\AA$, c = 7.2883(9) $\AA$, V = 1380.5(3) $\AA^3$, Z = 4. TiPO-2 crystallizes in triclinic space group P$\bar{1}$ with parameters a = 5.1620(10) $\AA$, b = 8.815(2) $\AA$, c = 10.655(3) $\AA$, $\alpha$ = $99.45^{\circ}$, $\beta$ = $102.94^{\circ}$, $\gamma$ = $91.06^{\circ}$, V = 465.34 $\AA^3$. TiPO-1 is constructed by infinite -Ti-O-Ti-O- linkage that is capped by $PO_4$ groups to form a chain structure with protonated DACH molecules occupying the interchain spaces. TiPO-2 represents a rare 3-D reduced titanophosphate with 12-MR channels. The structure of TiPO-2 is a neutral framework with water molecules located in the channels.

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References

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