Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Effects of Catalyst Promotion on the Selective Hydrogenation of Biphenol Using Various Pd/C Catalysts

  • Cho, Hong-Baek (Extreme Energy-Density Research Institute, Nagaoka University of Technology) ;
  • Hong, Bum-Eui (Division of Materials and Chemical Engineering, Hanyang University) ;
  • Park, Jai-Hyun (Division of Materials and Chemical Engineering, Hanyang University) ;
  • Ahn, Sung-Hyun (Division of Materials and Chemical Engineering, Hanyang University) ;
  • Park, Yeung-Ho (Division of Materials and Chemical Engineering, Hanyang University)
  • Published : 2008.12.20
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Abstract

The effect of sodium (Na) promotion was studied in the biphenol (BP) hydrogenation using various Pd/C catalysts. Different amounts of sodium metal were used for promotion with Pd/C and their effects on BP hydrogenation were observed. The promotion order was changed to compare the effect of the position of the promoter in relation to the palladium (Pd) metal on the catalytic activity and yield of the final product, bicyclohexyl-4,4'-diol (BHD). Pd/C catalysts prepared from different methods were also sodium-promoted and the changes of the reaction pathway according to the type of promoted Pd/C catalyst were compared.

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