Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts

  • Shon, Jeong-Kuk (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Sim, Jae-Yi (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Thakur, Santosh Singh (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Ko, Eun-Mi (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kong, Soo-Sung (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Choi, Ji-Yun (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kang, Min (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Senapati, Bidyut Kumar (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Choi, Doo-Seoung (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Ryu, Do-Hyun (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kim, Ji-Man (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University)
  • Published : 2008.10.20
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Abstract

In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

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References

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