Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Liquid-liquid Distribution of the Tetravalent Zirconium, Hafnium and Thorium with a New Tetradentate Naphthol-derivative Schiff Base

  • Saberyan, Kamal (Chemistry Research Department, Nuclear Science Research School, Nuclear Science and Technology Research Institute) ;
  • Shamsipur, Mojtaba (Department of Chemistry, Razi University) ;
  • Zolfonoun, Ehsan (Chemistry Research Department, Nuclear Science Research School, Nuclear Science and Technology Research Institute) ;
  • Salavati-Niasari, Masoud (Department of Chemistry, Kashan University)
  • Published : 2008.01.20
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Abstract

A fundamental study was developed concerning the novel solvent extraction of the tetravalent metal ions; zirconium(IV), hafnium(IV) and thorium(IV). Their extraction behavior in toluene was investigated with a recently synthesized naphthol-derivative Schiff base, 1-({[4-(4-{[(E)-1-(2-hydroxy-1-naphthyl)methyliden]amino}phenoxy) phenyl]imino}methyl)-2-naphthol (HAPMN). The spectrophotometrical examination of the complex formation between HAPMN and the Zr(IV), Hf(IV) and Th(IV) ions in acetonitrile revealed the formation of stable 1:1 complexes in the solution. After the thorium extraction in toluene, it was found that [Th(OH)3HA] was the respective deriving substance. While, in the case of zirconium and hafnium extraction, the extracted adduct was found to be [M4(OH)8(H2O)16Cl62HA]. The stoichiometric coefficients of these extracted species were determined by the slope analysis method. The extraction reaction followed a cation exchange mechanism.

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