Bulletin of the Korean Chemical Society

  • 제29권2호
  • /
  • Pages.313-318
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

  • Kawthekar, RahulB (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University) ;
  • Bi, Wentao (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University) ;
  • Kim, Geon-Joong (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University)
  • 발행 : 2008.02.20
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초록

An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

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참고문헌

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  4. Synthesis of Chiral Cyclic Carbonates via Kinetic Resolution of Racemic Epoxides and Carbon Dioxide vol.8, pp.1, 2016, https://doi.org/10.3390/sym8010004
  5. Superior Effect of Ultrasonic Homogenization to Mechanical Agitation on Accelerating Reaction Rates in Asymmetric Ring Opening of Epoxides vol.38, pp.7, 2017, https://doi.org/10.1002/bkcs.11174
  6. Catalyzed by a Chiral-at-Iridium Complex pp.18645631, 2019, https://doi.org/10.1002/cssc.201802049
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  10. Enantio-conversion and -selectivity of racemic atenolol kinetic resolution using free Pseudomonas fluorescens lipase (Amano) conducted via transesterification reaction vol.6, pp.31, 2016, https://doi.org/10.1039/c6ra01942k
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