Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

  • Kawthekar, RahulB (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University) ;
  • Bi, Wentao (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University) ;
  • Kim, Geon-Joong (Fine Material Synthesis Laboratory, Department of Chemical Engineering, Inha University)
  • Published : 2008.02.20
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Abstract

An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

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References

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