Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Catalytic Oxidation of Cyclohexene with Hydrogen Peroxide over Cu(II)-Cyclam-SBA-16 Catalyst

  • Prasetyanto, Eko Adi (Laboratory of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry, Inha University) ;
  • Park, Sang-Eon (Laboratory of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry, Inha University)
  • Published : 2008.05.20
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Abstract

A copper cyclam-type complex was successfully immobilized onto mesoporous silica SBA-16. Characterization by NIR spectroscopy and TGA analysis confirmed that copper cyclam complex is immobilized onto mesoporous SBA-16. The Cu(II)-Cyclam-SBA-16 was proven to be a good catalyst for oxidation reaction of cyclohexene with conversion up to 77.8% after 13 h reaction and providing a high selectivity to cyclohexenol and 3-hydroperoxycyclohex-1-ene. The results suggest that the copper species play a major role as catalyst via reversible redox cycles as proven by cyclic voltammetry analysis.

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