Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Coordination Polymers Consisting of Unusual Motifs. Synthesis and Properties of Silver(I) and Copper(II) Complexes of Triethanolaminetriisonicotinate

  • Noh, Tae-Hwan (Department of Chemistry, Pusan National University) ;
  • Lee, Jung-Woon (Department of Chemistry, Pusan National University) ;
  • Lee, Young-A (Department of Chemistry, Chonbuk National University) ;
  • Lee, Ji-Eun (Department of Chemistry, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry, Gyeongsang National University) ;
  • Jung, Ok-Sang (Department of Chemistry, Pusan National University)
  • Published : 2008.03.20
Download PDF
⟨ Previous Next ⟩

Abstract

Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO3)3 and the same treatment of Cu(NO3)2 with L gives 1D coordination polymer of [Cu(L)2](NO3)2. The nonrigid triethanolaminetriisonicotinate acts as a m 3-bridged tridentate for [Ag3(L)2](NO3)3 and a m 2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3- anions can be smoothly exchanged by PF6- anions in an aqueous suspension without destruction of the skeletal structure.

Keywords

References

  1. Blight, B. A.; Wisner, J. A.; Jennings, M. C. Angew. Chem., Int. Ed. 2007, 46, 2835 https://doi.org/10.1002/anie.200604724
  2. Gale, P. A. Coord. Chem. Rev. 2001, 213, 79 https://doi.org/10.1016/S0010-8545(00)00364-7
  3. Oh, M.; Mirkin, C. A. Nature 2005, 438, 651 https://doi.org/10.1038/nature04191
  4. Stang, P. J.; Olenyuk, B. Acc. Chem. Res. 1997, 30, 502 https://doi.org/10.1021/ar9602011
  5. Slone, R. V.; Yoon, D. I.; Calhoun, R. M.; Hupp, J. T. J. Am. Chem. Soc. 1995, 117, 11813 https://doi.org/10.1021/ja00152a027
  6. Chen, B.; Ockwig, N. W.; Fronczek, F. R.; Contreras, D. S.; Yaghi, O. M. Inorg. Chem. 2005, 44, 181 https://doi.org/10.1021/ic048612y
  7. Fujita, M. Chem. Soc. Rev. 1998, 27, 417 https://doi.org/10.1039/a827417z
  8. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Park, J. K.; Chae, H. K. J. Am. Chem. Soc. 2000, 122, 9921 https://doi.org/10.1021/ja001618b
  9. Albrecht, M. Angew. Chem., Int. Ed. 1999, 38, 3463 https://doi.org/10.1002/(SICI)1521-3773(19991203)38:23<3463::AID-ANIE3463>3.0.CO;2-E
  10. Jones, C. J. Chem. Soc. Rev. 1998, 27, 289 https://doi.org/10.1039/a827289z
  11. Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. 1998, 37, 1460 https://doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
  12. Constable, E. C. Tetrahedron 1992, 48, 10013 https://doi.org/10.1016/S0040-4020(01)89035-9
  13. Chui, S. S.-Y.; Lo, S. M.-F.; Charmant, J. P. H.; Orpen, A. G.; Williams, I. D. Science 1999, 283, 1148 https://doi.org/10.1126/science.283.5405.1148
  14. Kiang, Y.-H.; Gardener, G. B.; Lee, S.; Xu, Z. J. Am. Chem. Soc. 2000, 122, 6871 https://doi.org/10.1021/ja0009119
  15. Braga, D.; Grepioni, F. Acc. Chem. Res. 2000, 33, 601 https://doi.org/10.1021/ar990143u
  16. Schmidtchen, F. P.; Berger, M. Chem. Rev. 1997, 97, 1609 https://doi.org/10.1021/cr9603845
  17. Lapointe, R. E.; Roof, G. R.; Abboud, K. A.; Klosin, J. J. Am. Chem. Soc. 2000, 122, 9560 https://doi.org/10.1021/ja002664e
  18. Mason, S.; Cliford, T.; Seib, L.; Kuczera, K.; Bowman-James, K. J. Am. Chem. Soc. 1998, 120, 8899 https://doi.org/10.1021/ja9811593
  19. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Chae, H. K.; Jang, J. H.; Hong, J. Inorg. Chem. 2001, 40, 2105 https://doi.org/10.1021/ic001072u
  20. Jung, O.-S.; Park, S. H.; Kim, K. M.; Jang, H. G. Inorg. Chem. 1998, 37, 5781 https://doi.org/10.1021/ic980278g
  21. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Park, J. K.; Chae, H. K. J. Am. Chem. Soc. 2000, 122, 9921 https://doi.org/10.1021/ja001618b
  22. Jung, O.-S.; Kim, Y. J.; Kim, K. M.; Lee, Y.-A. J. Am. Chem. Soc. 2002, 124, 7906 https://doi.org/10.1021/ja026774s
  23. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Park, K. M.; Lee, S. S. Inorg. Chem. 2003, 42, 844 https://doi.org/10.1021/ic025935q
  24. Lee, Y.-A.; Kim, S. A.; Jung, S. M.; Jung, O.-S.; Oh, Y. H. Bull. Korean Chem. Soc. 2004, 25, 581 https://doi.org/10.1007/s11814-008-0098-y
  25. Jung, O.-S.; Lee, Y.-A.; Kim, Y. J. Chem. Lett. 2002, 1096
  26. Jung, O.-S.; Lee, Y.-A.; Kim, Y. J.; Hong, J. Cryst. Growth & Des. 2002, 2, 497 https://doi.org/10.1021/cg025555f
  27. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Kang, S. W.; Choi, S. N. Cryst. Growth & Des. 2004, 4, 23 https://doi.org/10.1021/cg0341048
  28. Park, B. I.; Chun, I. S.; Lee, Y.-A.; Park, K.-M.; Jung, O.-S. Inorg. Chem. 2006, 45, 4310 https://doi.org/10.1021/ic052053t
  29. Park, B. I.; Kim, Y. J.; Lee, Y.-A.; Park, K.-M.; Jung, O.-S. Bull. Korean Chem. Soc. 2004, 25, 1969 https://doi.org/10.5012/bkcs.2004.25.12.1969
  30. Cha, M. S.; Kim, S. A.; Yoo, K. H.; Park, K.-M.; Jung, O.-S. Bull. Korean Chem. Soc. 2006, 27, 137 https://doi.org/10.5012/bkcs.2006.27.1.137
  31. Chun, I. S.; Kwon, J. A.; Yoon, H. J.; Bae, M. N.; Hong, J.; Jung, O.-S. Angew. Chem., Int. Ed. 2007, 46, 4960 https://doi.org/10.1002/anie.200701152
  32. Yoon, H. J.; Chun, I. S.; Na, Y. M.; Lee, Y.-A.; Jung, O.-S. Chem. Commun. 2007, 492
  33. Hui, L.; Cha, M. S.; Lee, Y.-A.; Lee, S. S.; Jung, O.-S. Inorg. Chem. Commun. 2006, 10, 71 https://doi.org/10.1016/j.inoche.2006.09.006
  34. Sheldrick, G. M.; SHELXS-97: A Program for Structure Determination; University of Gottingen, Germany, 1997; Sheldrick, G. M. SHELXL-97: A Program for Structure Refinement; University of Gottingen, Germany, 1997
  35. Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1996, 118, 295 https://doi.org/10.1021/ja953438l
  36. Yaghi, O. M.; Li, H.; Davies, C.; Richardson, D.; Groy, T. L. Acc. Chem. Res. 1998, 31, 474 https://doi.org/10.1021/ar970151f

Cited by

  1. Direct anion effects on coordination polymerizations: construction and physicochemical properties of 1D, 2D, and 3D copper(II) coordination polymers containing 1,3,5-tris(isonicotinoylo vol.42, pp.31, 2008, https://doi.org/10.1039/c3dt51124c
  2. Synthesis, characterization, structural investigation, and antimicrobial studies of mononuclear Zn(II), Cd(II), and Ag(I) complexes of an N3O Schiff base vol.67, pp.18, 2008, https://doi.org/10.1080/00958972.2014.951346