Bulletin of the Korean Chemical Society

  • 제29권3호
  • /
  • Pages.562-566
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Coordination Polymers Consisting of Unusual Motifs. Synthesis and Properties of Silver(I) and Copper(II) Complexes of Triethanolaminetriisonicotinate

  • Noh, Tae-Hwan (Department of Chemistry, Pusan National University) ;
  • Lee, Jung-Woon (Department of Chemistry, Pusan National University) ;
  • Lee, Young-A (Department of Chemistry, Chonbuk National University) ;
  • Lee, Ji-Eun (Department of Chemistry, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry, Gyeongsang National University) ;
  • Jung, Ok-Sang (Department of Chemistry, Pusan National University)
  • 발행 : 2008.03.20
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초록

Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO3)3 and the same treatment of Cu(NO3)2 with L gives 1D coordination polymer of [Cu(L)2](NO3)2. The nonrigid triethanolaminetriisonicotinate acts as a m 3-bridged tridentate for [Ag3(L)2](NO3)3 and a m 2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3- anions can be smoothly exchanged by PF6- anions in an aqueous suspension without destruction of the skeletal structure.

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피인용 문헌

  1. Direct anion effects on coordination polymerizations: construction and physicochemical properties of 1D, 2D, and 3D copper(II) coordination polymers containing 1,3,5-tris(isonicotinoylo vol.42, pp.31, 2008, https://doi.org/10.1039/c3dt51124c
  2. Synthesis, characterization, structural investigation, and antimicrobial studies of mononuclear Zn(II), Cd(II), and Ag(I) complexes of an N3O Schiff base vol.67, pp.18, 2008, https://doi.org/10.1080/00958972.2014.951346