Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A New Selective Membrane Electrode for Oxalate Based on N,N'-Bis(salicylidene)-2,2-dimethylpropane-1,3-diamine Ni(II)

  • Ardakani, M.Mazloum (Department of Chemistry, Faculty of Science, Yazd University) ;
  • Iranpoor, F. (Department of Chemistry, Ardakan Payam Noor University) ;
  • Karimi, M.A. (Department of Chemistry, Faculty of Science, Shahid Bahonar University) ;
  • Salavati-Niasari, M. (Department of Chemistry, Faculty of Science, University of Kashan, Kashan, Iran)
  • Published : 2008.02.20
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Abstract

A new solvent polymeric membrane electrode, based on N,N'-bis(salicylidene)-2,2-dimethylpropane-1,3-diamine Ni(II) as the ionophore, was designed. The oxalate-selective electrode has the dynamic range between 1.0 10-6 M and 1.0 10-1 M with a Nernstian slope of -28.7 1.0 mV per decade. The detection limit was 6.3 10-7 M. The proposed electrode revealed good selectivities for oxalate over a variety of other anions and could be used in a pH range of 2.0-7.8. The electrode can be used for at least two months without any considerable divergence in potential. The designed electrode was applied as an indicator electrode in the potentiometric determination of oxalate in real samples.

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