The effect of heat treatment parameters on the emitter formation of the n-type silicon solar cell

n형 규소 태양전지 emitter형성에 미치는 열처리 변수의 영향

  • Shim, Ji-Myung (Department of Materials Science and Engineering, University of Incheon) ;
  • Kim, Young-Kwan (Department of Materials Science and Engineering, University of Incheon)
  • 심지명 (인천대학교 신소재공학과) ;
  • 김영관 (인천대학교 신소재공학과)
  • Published : 2008.10.31

Abstract

Employing screen printing technology, aluminum is applied to the back side of the n-type silicon wafer to see the effect of the heat treatment parameters on the Voc of the solar cell, Heat treatment at $850^{\circ}C$ produces the highest Voc among various heat treatment conditions. Heat treatment at the temperatures higher than $850^{\circ}C$ results in lower Voc, which is due to the destruction of the Al-Si alloy emitter layer. The destruction of Al-Si layer observed to be caused by the vigorous movement of silicon atoms toward aluminum layer during the heat treatment.

n형 실리콘를 이용히여 후면에 Al-emitter형성에 관해 �x처리조건이 Voc에 어떤 영향을 미치는지 알아보기 위하여 screen printing 방법으로 n-type Si 기판에 Al을 도포하였다. 열처기는 straight profile에서 50 inch/min의 belt speed로 $850^{\circ}C$의 peak temperature로 수행한 경우 가장 높은 Voc(585 mV)값을 보였고, 이 온도보다 낮은 경우에 불 균일한 Al-Si alloy 층이 형성되고, 이 온도보다 높은 경우에 Al층으로 Si 원자의 이동이 극심하게 발생되어 Al-Si alloy층이 파괴되는 현상으로 인하여 Voc가 감소함을 보았다.

Keywords

References

  1. R. Kopecek, T. Buck, J. Libal, I. Rover, K. Wambach, L. J. Geerlings, P. Sanchez-Friera, J. Alonso, E. Wefringhaus and P. Fath, "Large area screen printed N-type silicon solar cells with rear Aluminium emitter: Efficiencies exceeding 16%", IEEE 4th WCPEC (2006)
  2. D. MacDonald and L.J. Geerligs, Applied Physics Letter 85 (2004) https://doi.org/10.1063/1.1767954
  3. J.E. Cotter et al., 15th Workshop on Crystalline Silicon solar cells & Modules: Materials and Processes (2005)
  4. C. Schmiga, A. Froitzheim, M. Ghosh, A. Merz, J. Schmidt and R. Brendel, "Solar cells on n-type silicon materials with screen printed rear aluminium-$p^+$emitter", 20th PVSEC (2005)
  5. C. Schmiga, A. Froitzheim, M. Ghosh, A. Merz, J. Schmidt and R. Brendel, "Advances in the manufacturing of n-type silicon solar cells with screen printed aluminium alloyed rear emitter", 21th PVSEC (2006)
  6. J.W. Mayer and S.S Lau, "Electronic Materials Science : For Integrated Circuits in Si and GaAs", (1988) 283