DOI QR코드

DOI QR Code

활성탄 고정층에서 2성분 혼합가스의 종류와 혼합 분율에 따른 포화 흡착량의 변화

Variations of Equilibrium Adsorption Capacities According to Type and Mixing Fraction of Binary Mixed Gas on Activated Carbon Fixed-bed

  • 김효원 (부경대학교 응용화학공학부) ;
  • 이송우 (부경대학교 응용화학공학부) ;
  • 이민규 (부경대학교 응용화학공학부) ;
  • 천재기 (부경대학교 응용화학공학부)
  • Kim, Hyo-Won (Division of Applied Chem. Eng., Pukyong National University) ;
  • Lee, Song-Woo (Division of Applied Chem. Eng., Pukyong National University) ;
  • Lee, Min-Gyu (Division of Applied Chem. Eng., Pukyong National University) ;
  • Cheon, Jae-Kee (Division of Applied Chem. Eng., Pukyong National University)
  • 발행 : 2007.10.31

초록

Adsorption experiments of binary mixed gases composed of acetone/methylethylketone (MEK), MEK/benzene, MEK/toluene, and benzene/toluene were carried out on activated carbon fixed-bed. The variations of equilibrium adsorption capacity according to type and fraction of binary gas were investigated. In case of binary gases composed of acetone/MEK and benzene/toluene, equilibrium adsorption capacities of MEK and toluene were increased according to the increase of fraction of MEK and toluene, but equilibrium adsorption capacities of acetone and benzene were decreased. In case of binary gases composed of MEK/benzene and MEK/toluene, equilibrium adsorption capacities of benzene and toluene were increased according to the increase of fraction of benzene and toluene, but equilibrium adsorption capacities of MEK was decreased.

키워드

참고문헌

  1. Ruthven D. M, 1984, Principles of adsorption and adsorption process, Wiley, New York.
  2. Bansal R. C., Goyal M., 2005, Activated carbon adsorption, CRC Press, Boca Raton, FL
  3. Khan F. I., Ghoshal A. K., 2000, Removal of volatile organic compound from polluted air, Journal of Loss Prevention in the Process Industries, 13, 527-545 https://doi.org/10.1016/S0950-4230(00)00007-3
  4. Lee S. W., Kwon J. H., Na Y. S., Choi D. H., Ryu D. C., Song S. K., 2000, Characteristics of pore structure of steam activated carbon with carbonization temperature, J. Environ. Sci., 9(4), 345-349
  5. Lee S. W., Na Y. S., Kim D. H., Choi D. H., Ryu D. C., Song S. K., 2000, Characteristics of steam activated carbon made from Youngwall coal, J. Environ. Sci., 9(4), 339-343
  6. Lee S. W., Moon J. C., Kim D. H., Lee C. H., Choi D. ., Ryu D. C., Song S. K., 2000, The variation of pore size distribution of the coalbased extruded activated carbon, J. Environ. Studies, 18, 55-59
  7. Lee S. W., Moon J. C., Lee C. H., Choi D. H., Ryu D. C., Song S. K., 2000, Variation of pore structure of coal-based activated carbon with burn-off of steam activation, J Korean Soc. Environ. Engrs, 22(2), 2141-2148
  8. Lee S. W., Moon J. C., Lee C. H., Ryu, D. C. Choi D. H., Ryu B. S., Song S. K., 2001, Analysis of pore characteristics between commercial activated carbons and domestic anthracite- based activated carbon, J. Korean Soc. Environ. Engrs, 23(7), 1211-1218
  9. Lee S. W., Na Y. S., Kim D. H., Choi D. H., Ryu D. C., Song S. K., 2002, Pore characteristics of anthracite-based activated carbon according to granulation process, HWAHAK KONGHAK, 40(1), 128-132
  10. Lee S. W., Bae S. K., Kwon J. H., Na Y. S., An C. D., Yoon Y. S., Song S. K., 2005, Correlations between pore structure of activated carbon and adsorption characteristics of acetone vapor, J. Korean Soc. Environ. Engrs, 27(6), 620-625
  11. Lee S. W., Kwon J. H., Kang J. H., Na Y. S., An C. D., Yoon Y. S., Song S. K., 2006, Adsorption characteristics of toluene vapor according to pore size distribution of activated carbon, J. Environ. Sci., 15(7), 695-699 https://doi.org/10.5322/JES.2006.15.7.695
  12. Lim J. K., Lee S. W., Kam S. K., Lee D. W., Lee M. G., 2005, Adsorption characteristics of toluene vapor in fixed-bed activated carbon column, J. Environ. Sci., 14(1), 61-69 https://doi.org/10.5322/JES.2005.14.1.061
  13. Huang Z., Kang F., Liang K., Hao J., 2003, Breakthrough of methylketone and benzene vapors in activated carbon fiber beds, J. Hazard. Mater., B98, 107-115
  14. Lee M. G., Lee S. W., Lee S. H., 2006, Comparison of vapor adsorption characteristics of acetone and toluene based on polarity in activated carbon fixed-bed reactor, Korean J. Chem. Eng., 23(5), 773-778 https://doi.org/10.1007/BF02705926
  15. Lee S. W., Kam S. K., Lee M. G., 2007, Comparison of breakthrough characteristics for binary vapors composed of acetone and toluene based on adsorption intensity in activated carbon fixed-bed reactor, J. Ind. Eng. Chem., in press
  16. Kim H. S., Park Y. S., 2003, Binary component adsorption characteristics of benzene and toluene at the fixed-bed adsorption column with activated carbon, J. Korean Soc. Environ. Engrs, 25, 977-983
  17. Park J. T., Kim J. S., Chung K. H., Moon H., Seo G., 1994, Gaseous adsorption properties of n-hexane, methylethylketone and toluene on granular activated carbon, HWAHAK KONGHAK, 32(3), 476-482
  18. Micromeritics, 1997, ASAP 2010 Manual, Appendix C
  19. Allan F., Barton M., 2000, CRC Table of solubility parameters and other cohesion parameters, CRC Press, Inc. Boca Raton, Florida

피인용 문헌

  1. Variations of Adsorption Characteristics of Binary Vapor According to Packing System of Double-layer Adsorption Bed vol.21, pp.3, 2012, https://doi.org/10.5322/JES.2012.21.3.305