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Preparation of Activated Carbon from Waste Citrus Peels by ZnCl2

ZnCl2를 이용하여 폐감귤박으로부터 활성탄 제조

  • Kang, Kyung-Ho (Division of Civil & Environmental Engineering, Cheju National University) ;
  • Kam, Sang-Kyu (Division of Civil & Environmental Engineering, Cheju National University) ;
  • Lee, Min-Gyu (Division of Applied Chemical Engineering, Pukyong National University)
  • 강경호 (제주대학교 토목환경공학) ;
  • 감상규 (제주대학교 토목환경공학) ;
  • 이민규 (부경대학교 응용화학공학부)
  • Published : 2007.09.30

Abstract

Activated carbon was prepared from waste citrus peels by chemical activation with $ZnCl_2$. The optimal condition of carbonization was at $300^{\circ}C$ for 1.5 hr. Activation experiments with carbonized samples prepared at optimal carboniztion condition were carried out under various conditions such as activation temperature of 400 to $900^{\circ}C$, activation time of 0.5 to 2.0 hr, and $ZnCl_2$ ratio of 100 to 300%. In order to investigate the physical properties of the activated carbons prepared, iodine adsorptivities and specific surface areas were measured and their morphologies were observed from scanning electron microscopy. As $ZnCl_2$ ratio increased, activation yield decreased, while iodine adsorptivity and specific surface area increased. The optimal condition of activation was at 300% $ZnCl_2$ ratio and $300^{\circ}C$ for 1.5 hr, and then iodine adsorptivity and specific surface area was measured as about 862 mg/g and $756m^2/g$, respectively. SEM photography showed that the surface morphology was changed and many active pore were produced by chemical activation.

Keywords

References

  1. Gergova K, Petrov N., Minkova Y, 1993, A comparison of adsorption characteristics of various activated carbons, J Chern. Tech.Biotechnol., 56(l), 77-82
  2. lley M., Marsh H., Reinoso F. R., 1973, The adsorptive properties of carbonised olive stones, Carbon, 11(6), 633-636 https://doi.org/10.1016/0008-6223(73)90330-8
  3. Avom J, Mbadcam J. K, Noubactep C., Germain P., 1997, Adsorption of methylene blue from an aqueous solution on to activated carbons from palm-tree corps, Carbon, 35(3), 365-369 https://doi.org/10.1016/S0008-6223(96)00158-3
  4. Girgis B. S., Khalil C. B., Tawfik T. A. M., 1994, Activated carbon from sugar cane bagasse by carbonization in the presence of inorganic acids, J. Chern. Tech. Biotechnol., 61(1), 87-92 https://doi.org/10.1002/jctb.280610113
  5. Reinoso F. R., Molina-Sabio M., 1992, Activated carbons from lignocellulosic materials by chemical and/or physical activation: an overview, Carbon, 30(7), 1111-1118 https://doi.org/10.1016/0008-6223(92)90143-K
  6. Bin H. S., Baek I. H., Kim T. Y, Roo W. H., 1999, Adsorption of surfactant on activated carbons using agricultural wastes as raw materials, J. Korea Solid Wastes Eng. Soc., 16(2), 173-180
  7. Kim H. R., Lee J. M., Ghung M. K, 2003, Preparation of activated carbons from rice hull by NaOH and KOH activation, J. Korean Ind. Eng. Chern., 14(4), 381-385
  8. Kim J. H., Bae W. K, 2003, Granular activated carbons from jujube seeds and walnut shells and their adsorption characteristics, J.Korea Soc. Waste Manage., 20(5), 521-528
  9. Lee S. H., Lee B. H., Park H. J. 2001, Study on the production of activated carbon using Chinese cabbage, J. Korean Environ. Sci. Soc., 10(5), 373-380
  10. You S. H., Kim H. H., 1998, The preparation of activated carbon from coffee waste : $ZnCl_{2}$- activation, J. Korean Ind. Eng. Chern., 9(4), 509-515
  11. Lim S. B., J wa M. K, 2003, Optimization in extraction conditions of carotenoids from citrus unshiu press cake by supercritical carbon dioxide, Korean J. Food Sci. Technol., 35(6), 1104-1109
  12. Oh D. H., Lee M. H., Park Y Y, 1981, A study on the feeding value of citrus pulp, Korean J. Anim. Sci., 23(4), 277-283
  13. Savador F., Sanchez J c., 1996, A new method for regenerating activated carbon by thermal desorption with liquid water under subcritical conditions, Carbon, 34(4), 511-516 https://doi.org/10.1016/0008-6223(95)00211-1
  14. Choi J. M., 2006, Characteristics of carbonation and activation for waste citrus peels, Master Thesis, Dept. of Fine Chemistry, Seoul National University of Technology, Seoul, p53
  15. Ahmadpour A, Do D. D., 1996, The preparation of active carbons from coal by chemical and physical activation, Carbon, 34(4). 471-479 https://doi.org/10.1016/0008-6223(95)00204-9
  16. Mattson J. S., Mark H. B., 1971, Activated carbon: surface chemistry and adsorption from solution, Marcel Dekker, Inc., New York, p237
  17. Zhonghua H., Vansant E. F., 1995, A new composite adsorbent produced by chemical activation of elutrilithe with zinc chloride, J.Colloid Interface Sci., 176(2), 422-431 https://doi.org/10.1006/jcis.1995.9949
  18. Lee Y. D., Kang H. Y, Kim J. C., 1999, Production of waste sludge activated carbon using a rotary kiln reactor and chemical activation. J. Korea Solid Wastes Eng. Soc., 16(5), 507-517
  19. Kim S. c., Hong I. K., 1998, Manufacturing and physical properties of coal based activated carbon, J. Korean Soc. Environ. Eng., 20(5), 745-754
  20. Lee J. J., Yu Y H., 2001, Adsorption characteristics of activated carbon manufactured from waste sludge of paper mill, J. Korean Soc. Environ. Eng., 23(10), 1659-1665
  21. Ahmadpour A, Do D. D., 1997, The preparation of activated carbon from macadamia nutsshell by chemical activation, Carbon, 35(12), 1723-1732 https://doi.org/10.1016/S0008-6223(97)00127-9
  22. Laine B., Calafast A, 1991, Factors affecting the preparation of activated carbons from coconut shell catalized by potassium, Carbon, 29(7), 949-953 https://doi.org/10.1016/0008-6223(91)90173-G
  23. Bansal R. C., Donnet J. B., Stoeckli F., 1988, Active carbon, Dekker, New York, p482
  24. Brunauer S., Emmett P. H., Deming W. S., Teller E., 1940, On a theory of the van der waals adsorption of gases, J. Amer. Chern.Soc., 62(7), 1723-1732 https://doi.org/10.1021/ja01864a025

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