DOI QR코드

DOI QR Code

Electrical and Optical Properties of Red Phosphorescent Top Emission OLEDs with Transparent Metal Cathodes

투명 금속 음극을 이용한 전면발광 적색 인광 OLEDs의 전기 및 광학적 특성

  • 김소연 (순천향대학교 신소재공학과) ;
  • 하미영 (순천향대학교 신소재공학과) ;
  • 문대규 (순천향대학교 신소재공학과) ;
  • 이찬재 (전자부품연구원 디스플레이센터) ;
  • 한정인 (전자부품연구원 디스플레이센터)
  • Published : 2007.09.01

Abstract

We have developed red phosphorescent top emission organic light-emitting diodes with transparent metal cathodes deposited by using thermal evaporation technique. Phosphorescent guest molecule, BtpIr(acac), was doped in host CBP for the red phosphorescent emission, Ca/Ag, Ba/Ag, and Mg/Ag double layers were used as cathode materials of top emission devices, which were composed of glass/Ni/2TNATA(15 nm)/${\alpha}$-NPD(35 nm)/CBP:BtpIr(acac)(40 nm, 10%)/BCP(5 nm)/$Alq_3$(5 nm)/cathodes. The optical transparencies of these metal cathodes strongly depend on underlying Ca, Ba, and Mg layers. These layers also strongly affect the electrical conduction and emission properties of the red phosphorescent top emission devices.

Keywords

References

  1. C. W. Tang and S. A. VanSlyke, 'Organic electroluminescent diodes', Appl. Phys. Lett., Vol. 51, No. 12, p. 913, 1987 https://doi.org/10.1063/1.98799
  2. 정동희, 김상걸, 홍진웅, 이준웅, 김태완, '버퍼층과 음전극에 따른 유기 발광 소자의 전기적 특성과 발광 효율', 전기전자재료학회논문지, 16권, 5호, p. 409, 2003
  3. N. Ibaraki and M. Kobayashi, 'Views on the present and future promise of OLED displays', SID'06 Digest, p. 1760, 2006
  4. A. Nathan, A. Kumar, K. Sakariya, P. Servati, and A. Sazonov, 'Amorphous silicon back-plane electronics for OLED displays', IEEE J. Select. Topics Quantum Elect., Vol. 10, No. 1, p. 58, 2004 https://doi.org/10.1109/JSTQE.2004.824105
  5. T. Suzuki, 'Flat panel displays for ubiquitous product applications and related impurity doping technologies', J. Appl. Phys., Vol. 99, p. 111101, 2006 https://doi.org/10.1063/1.2199753
  6. T. Sasaoka, M. Sekiya, A. Yumoto, J. Yamada, T. Hirano, Y. Iwase, T. Yamada, T. Ishibashi, T. Mori, M. Asano, S. Tamura, and T. Urabe, 'A 13.0-inch AM-OLED display with top-emitting structure and adapative current mode programmed pixel circuit (TAC)', SID'01 Digest, p. 384, 2001
  7. G. Gu, V. Bulovic, P. E. Burrows, S. R. Forrest, and M. E. Thompson, 'Transparent organic light emitting devices', Appl. Phys. Lett., Vol. 68, No. 19, p. 2606, 1996 https://doi.org/10.1063/1.116196
  8. G. Parthasarathy, C. Adachi, P. E. Burrows, and S. R. Forrest, 'High-efficiency transparent organic light-emitting devices', Appl. Phys. Lett., Vol. 76, No. 15, p. 2128, 2000 https://doi.org/10.1063/1.126275
  9. P. E. Burrows, G. Gu, S. R. Forrest, E. P. Vicenzi, and T. X. Zhou, 'Semitransparent cathodes for organic light emitting devices', J. Appl. Phys., Vol. 87, No. 6, p. 3080, 2000 https://doi.org/10.1063/1.372303
  10. G. Parthasarathy, P. E. Burrows, V. Khalfin, V. G. Kozlov, and S. R. Forrest, 'A metal-free cathode for organic semiconductor devices', Appl. Phys. Lett., Vol. 72, No. 17, p. 2138, 1998 https://doi.org/10.1063/1.121301
  11. L. S. Hung, C. W. Tang, M. G. Mason, P. Raychaudhuri, and J. Madathil, 'Application of an ultrathin LiF/Al bilayer in organic surface-emitting diodes', Appl. Phys. Lett., Vol. 78, No. 4, p. 544, 2001 https://doi.org/10.1063/1.1327273
  12. R. B. Pode, C. J. Lee, D. G. Moon, and J. I. Han, 'Transparent conducting metal electrode for top emission organic light-emitting devices: Ca-Ag double layer', Appl. Phys. Lett., Vol. 84, No. 23, p. 4604, 2004
  13. Y. Q. Li, J. X. Tang, Z. Y. Xie, L. S. Hung, and S. S. Lau, 'An efficient organic light-emitting diode with silver electrodes', Chem. Phys. Lett., Vol. 386, p. 128, 2004 https://doi.org/10.1016/j.cplett.2004.01.049
  14. T. F. Guo, F. S. Yang, Z. J. Tsai, G. W. Feng, T. C. Wen, S. N. Hsieh, C. T. Chung, and C. I. Wu, 'High-brightness top-emissive polymer light-emitting diodes utilizing organic oxide/Al/Ag composite cathode', Appl. Phys. Lett., Vol. 89, No. 5, p. 051103, 2006 https://doi.org/10.1063/1.2234317
  15. 문대규, 이찬재, 한정인, 'Ba/Ag 투명 음극을 이용한 전면발광 OLEDs의 전기 및 광학적 특성', 전기전자재료학회논문지, 19권, 9호, p. 873, 2006 https://doi.org/10.4313/JKEM.2006.19.9.873
  16. S. M. Sze, 'Physics of semiconductor devices', Wiley, p. 251, 1981
  17. C. J. Lee, R. B. Pode, J. I. Han, and D. G. Moon, 'Cal/Ag bilayer cathode for transparent white organic light-emitting devices', Appl. Surf. Sci., Vol. 253, p. 4249, 2007 https://doi.org/10.1016/j.apsusc.2006.09.026