DOI QR코드

DOI QR Code

The Effect of Thermal Decomposition of Epoxy Resin for a Variation of Hardener

에폭시수지의 경화제 변화량에 따르는 열분해 영향

  • Park, Keun-Ho (Dept. of Chemical Engineering, Chang-Won National University) ;
  • Lee, Yong-Sook (Nation Emergency Management Agency All Rights Reserved) ;
  • Song, Ju-Yeong (Dept. of Chemical Engineering, Chang-Won National University) ;
  • Lee, Soo (Dept. of Chemical Engineering, Chang-Won National University) ;
  • Kim, Sung-Il (R&D center, Samchun Pure Chemical Ind. Co., LTD)
  • 박근호 (창원대학교 공과대학 화공시스템공학과) ;
  • 이용숙 (소방방재청 화재조사팀) ;
  • 송주영 (창원대학교 공과대학 화공시스템공학과) ;
  • 이수 (창원대학교 공과대학 화공시스템공학과) ;
  • 김성일 (삼전화학)
  • Published : 2007.12.31

Abstract

We investigated heat stability of epoxy resin products and epoxy resin according to the influence hardener. The heat flow which shows the degree of thermal decomposition of the epoxy resin product and epoxy resin measured by using the differential scanning calorimeter (DSC). As a result, we found that in the case of heat stability for epoxy resin as hardener was added, the ratio of one to one (epoxy resin : hardener) was the most suitable in air condition and nitrogen atmosphere.

Keywords

References

  1. S. H. Cho, S. C. Oh, J. B. Do, S. GyRo, and H. S. Park, A Study on the Prolonged Time Heat Resistanse of Epoxy Resin Based Neutron Shielding Materials, Applied Chemistry, 9(6), 884 (1998)
  2. E. Sharmin, L. Imo, and S. M. A. Ahmad, Acrylic-melamine modified DGEBA-epoxy coatings and their anticorrosive behavior, Progress in organic coatings 50, 47 (2004) https://doi.org/10.1016/j.porgcoat.2003.10.003
  3. A. Balabanovich, A. Hornung, D. Merz, and H. Seifert, The effect of a curing agent on the thermal degradation of fire retardant brominated epoxy resins, Science Direct Polymer Degradation and Stability, 85, 713 (2004) https://doi.org/10.1016/j.polymdegradstab.2004.02.012
  4. G. V. Assche, B. V. Mele, and Y. Saruyama, Frequency dependent heat capacity in the cure of epoxy resins, Thermochimica Acta, 377, 125 (2001) https://doi.org/10.1016/S0040-6031(01)00547-0
  5. Metha Rutnakornpituk, Modification of epoxy-novolacresins with polysiloxane containing nitrile functional groups synthesis and characterization, European Polymer journal, 41, 1043 (2005) https://doi.org/10.1016/j.eurpolymj.2004.11.013
  6. 大阪市立工業硏究所, 日本Plastics 技術協會 (K. Y. Lee and H. K. Moon 共譯), 最新 Plastics 技術, Sungandang, Seoul, pp.1043-1052 (2001)
  7. Y. S. Lee and K. H. Park, A Study on the Thermal Stability of Chemical Products using Thermosetting Resin, Engineering Research & Technology, 5, 377 (2005)
  8. Chemical Engineering Research Information Center, DSC (Differential Scanning Calorimeter), 3rd, Seoul, pp.25-28 (1980)
  9. S. H. Shin, M. H. Suh, S. H. Lee, J. E. Yie, and J. W. Lee, A Study on Curing Kinetics of Unsaturated Polymer Resin, Hwahak Konghak, 25(5), 522 (1987)
  10. M. S. Park, B .C. Chun, D. W. Kang, and D. S. Lee, Polymer chemistry : an introduction, Freedom Academy Pub. Co., Seoul, p. 354, 447, 452, 459 (1997)