High-Temperature Oxidation Behavior of Commercial Pure Titanium in Mixed Gases

혼합가스 분위기 중에서 공업용 순 타이타늄의 고온산화 거동

  • 박성호 (부경대학교 대학원 신소재공학부) ;
  • 안용식 (부경대학교 신소재공학부)
  • Published : 2007.05.31

Abstract

The oxidation behavior of commercial pure titanium is investigated in the temperature range of $727^{\circ}C{\sim}950^{\circ}C$ in mixed gases. The weight change is measured by TGA during oxidation in mixed gases. The oxidation behavior indicated by weight gain or the growth of oxide layer is based on the linear rate law at high temperatures. The structure of the oxide scale formed during oxidation is analysed by optical microscopy, electron probe microanalyzer, scanning electron microscope and x-ray diffraction. Oxide scales have a $TiO_2$ structure, and are constituted with multi-layered or two layered porous external one and a dense internal one. Ti-O solid solution region is formed at the interface of metal and scale layer. The formation of oxide scale is influenced by the oxidation temperature, time, crystal structure and the condition of atmosphere.

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