DOI QR코드

DOI QR Code

Photocatalytic Decolorization of Dye Using Packed-bed Reactor and Immobilized TiO2/UV System

충전층 반응기와 고정화 TiO2/UV를 이용한 Rhodamine B의 광촉매 탈색

  • Published : 2007.03.28

Abstract

The photocatalytic decolorization of Rhodamine B (RhB) was studied using packed-bed reactor and immobilized $TiO_2/UV$ System. The 20 W UV-A, UV-B and UV-C lamps were employed as the light source. The effect of shape and surface polishing extent of reflector, distance between the reactor and reflector, reactor material were investigated. The results showed that the order of the initial reaction constant with reflector shape was round > polygon > W > rhombus. The optimum distance between the reactor and reflector was 2 cm. The initial reaction constant of quartz reactor was 1.46 times higher than that of tile PVDF reactor.

Keywords

References

  1. Harmer, C. and Bishop, P., 1992, Transformation of Azo dye AO-7 by wastewater biofilms, Wat. Sci. Tech., 36(3/4), 627-636
  2. Bishop, P. L. and Fitzgerald, S. W., 1995, Two stage anaerobic treatment of sulfonated Azo dyes, J. Environ. Sci. Health, A30(6), 1251-1276
  3. Hans G. K., Klausener, F., Meyer, U., Ludeke, B., and Leisinger, T., 1983, Influence of aromatic sulfo groups in the microbial degradation of the Azo dyes Orange 1 and Orange 2, Arch. Microbio., 135, 1-7 https://doi.org/10.1007/BF00419473
  4. Pagga, U. and Brown, B., 1987, The degradation of dyestuffs : part Il - behaviour of dyestuffs biodegradation tests, Chemosphere, 16, 1539-1543 https://doi.org/10.1016/0045-6535(87)90094-4
  5. 강준원, 박훈수, 최광호, 1995, 이산화티타늄 광촉매에서의 광분홰반응에 의한 유기물 제거에 관한 연구, 대한환경공학회지, 17(3), 283-294
  6. Matthews, R. W., 1986, Photo-oxidation of organic material in aqueous suspensions of titanium dioxide, Wat. Res., 20(5), 569-578 https://doi.org/10.1016/0043-1354(86)90020-5
  7. Fox, M. A. and Dulay, M. T., 1993, Heterogeneous photocatalysis, Chern. Rev., 93, 341-357 https://doi.org/10.1021/cr00017a016
  8. Tang, W. Z. and An, H., 1995, UV/Ti$O_{2}$ photocatalytic oxidation of commercial dyes in aqueous solutions, Chemosphere, 31, 4157-4170 https://doi.org/10.1016/0045-6535(95)80015-D
  9. 황규대, 황선진, 이지웅, 2001, UV /Ti$O_{2}$를 이용한 Acid Red 337의 광산화반응에서 운전조건변화가 분해속도에 미치는 영향, 한국물환경학회지, 17(3), 357-367
  10. 박영식, 안갑환, 2003, GF/C에 고정된 Ti$O_{2}$와 유동층 반응기를 이용한 Rhodamine B의 광촉매탈색, 한국환경과학회지, 12(12), 1277-1284
  11. 김종향, 남춘동, 김병관, 1996, Ti$O_{2}$ 고정화 지지체를 이용한 Chlorothalonil의 광촉매분해, 공업화학, 7(4), 750-756
  12. Jung, O. J, Choi, H. I, and Cheong, K. H., 2002, Degradation of some chlirophenols by coated $TiO_{2}$ photoreactor, Environ., Eng.,Res., 7(1), 1-9 https://doi.org/10.4491/eer.2002.7.1.001
  13. 조일형, 김현용, 성기석, 박경칠, 이홍근, 2001, 태양광/Ti$O_{2}$ 시스템을 이용한 수중의 중금속-EDTA 제거에 관한 연구, 한국물환경학회지, 17(1), 35-46
  14. Kim D. S., and Park, Y. S., 2006, Photocatalytic decolorization of Rhodamine B by immobilized $TiO_{2}$ onto silicone sealant, Chem Eng. J., 116, 133-137
  15. 박영식, 2004, UV/Ti$O_{2}$와 유동층 반응기를 이용한 안료의 광촉매 탈색, 한국환경과학회지, 13(10), 921-928
  16. Herrmann, J. M., Disdier, J., Pichat, P., Malato, S. and Blanco, J., 1998, TiO--based solar photocatalytic detoxification of water containing organic pollutants,. Case studies of 2,4-dichlorophenoxyaceticacid(2,4-D) and of benzofuran, Appl, Catal., B, 17, 15-23 https://doi.org/10.1016/S0926-3373(97)00098-2
  17. Robert, D, and Malato, S., 2002, Solar photocatalysis: a clean process for water detoxification, The Sci. of the Tot. Environ., 192, 85-97
  18. Ajona, J. I. and Vidal, A, 2000, The use of CPC collectors for detoxification of contaminated water: design, construction and preliminary results', Sol. Energy, 68(1), 109- 120 https://doi.org/10.1016/S0038-092X(99)00047-X
  19. Rodriguez, S. M., Richer, C., Galvez, J. B., and Vincent, M., 1996, Photocatalyic degradaton of industrial residual waters, Sol. Energy, 56(5), 401-410 https://doi.org/10.1016/0038-092X(96)00023-0