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Analysis on the Electrical.optical Properties and fabrication of OLED with AZO Anode Electrode

AZO Anode 전극을 적용한 OLED 소자의 제작과 전기적.광학적 특성 분석

  • 진은미 (원광대학교 전기전자 및 정보공학부) ;
  • 신은철 (홍익대학교 정보디스플레이공학과) ;
  • 김태완 (홍익대학교 정보디스플레이공학과) ;
  • 박춘배 (원광대학교 전기전자 및 정보공학부)
  • Published : 2007.04.01

Abstract

AZO(Aluminum-doped Zinc Oxide) films are attractive materials as transparent conductive electrode because they are inexpensive, nontoxic and abundant element compared with ITO(Indium Tin Oxide). AZO films have been deposited on glass (corning 1737) substrates by RF magnetron sputtering. The AZO film was post-annealed at $600^{\circ}C$ for 2 hr with $N_2$ atmosphere. The AZO films were used as an anode contact to fabricate OLEDs(Organic Light Emitting Diodes). OLEDs with $AZO/TPD/Alq_3/Al$ configuration were fabricated by thermal evaporation. We investigated that the electric, structural and optical properties of AZO thin films, which measured using the methods of XRD, SEM, Hall measurement and Spectrophotometer. The current density-voltage and luminescence-voltage properties of devices were studied and compared with ITO devices fabricated under the same conditions.

Keywords

References

  1. C. M. Aguirre, S. Auvray, S. Pigeon, R. Izquierdo, P. Desjardins, and R. Martel, 'Carbon nanotube sheets as electrodes in organic light-emitting diodes', Appl, Phys, Lett., Vol. 88, No. 18, p. 183104, 2006 https://doi.org/10.1063/1.2199461
  2. X. Buwen, S. Yafeng, M. Meng, and L. Chuannan, 'Enhancement of hole injection with an ultra-thin $Ag_{2}O$ modified anode in organic light-emitting diodes', Microelectronics Journal, Vol. 36, No. 2, p. 105, 2005 https://doi.org/10.1016/j.mejo.2004.11.006
  3. H. W. Choi, S. Y. Kim, K. B. Kim, Y. H. Tak, and J. L. Lee, 'Enhancement of hole injection using $O_{2}$ plasma-treated Ag anode for top-emitting organic light-emitting diodes', Appl. Phys. Lett., Vol. 86, No.1, p. 012104, 2005 https://doi.org/10.1063/1.1846149
  4. H. Aziz and Z. D. Popovic, 'Degradation phenomena in small-molecule organic light-emitting devices', Chem. Mater., Vol. 16, No. 23, p. 4522, 2004 https://doi.org/10.1021/cm040081o
  5. R. H. Young, C. W. Tang, and A. P. Marchetti, 'Current-induced fluorescence quenching in organic light-emitting diodes', Appl. Phys. Lett., Vol. 80, No. 5, p. 874, 2002 https://doi.org/10.1063/1.1445271
  6. 한진우, 강희진, 김종연, 서대식, '고분자 기판위에 유기 용매를 사용하지 않은 다충 박막 Encapsulation 기술 개발', 전기전자재료학회논문지, 19권, 8호, p. 754, 2006 https://doi.org/10.4313/JKEM.2006.19.8.754
  7. J. Li, M. Yahiro, K. Ishida, H. Yamada, and K. Matsushige, 'Enhanced performance of organic light emitting device by insertion of conducting/insulating $WO_{3}$ anodic buffer layer', Synth, Met., Vol. 151, No. 2, p. 141, 2005 https://doi.org/10.1016/j.synthmet.2005.03.019
  8. 김경민, 진은미, 박춘배, 'LED 효율 향상을 위한 Texture구조 AZO 박막의 제조와 광학적 특성분석', 전기전자재료학회논문지, 19권, 10호, p. 901, 2006 https://doi.org/10.4313/JKEM.2006.19.10.901
  9. T. W. Kim, D. C. Choo, Y. S. No, W. K. Choi, and E. H. Choi, 'High work function of Al-doped zinc-oxide thin films as transparent conductive anodes in organic light-emitting devices', Applied Surface Science, Vol. 253, No. 4, p. 1917, 2006 https://doi.org/10.1016/j.apsusc.2006.03.032
  10. H. Jiang, Y. Zhou, B. S. Ooi, Y. Chen, T. Wee, Y. L. Lam, J. Huang, and S. Liu, 'Improvement of organic light-emitting diodes performance by the insertion of a $Si_{3}N_{4}$ layer', Thin Solid Films, Vol. 363, No. 1, p. 25, 2000 https://doi.org/10.1016/S0040-6090(99)00975-X
  11. K. Tamano, D. C. Cho, T. Mori, T. Mizutani, and M. Sugiyama, 'Enhancement of hole injection by metal anode in organic light-emitting diodes', Thin Solid Films, Vol. 438, No .2, p. 182, 2003 https://doi.org/10.1016/S0040-6090(03)00731-4
  12. D. Xu, Z. Deng, Y. Xu, J. Xiao, C. Liang, Z. Pei, and C. Sun, 'An anode with aluminum doped on zinc oxide thin films for organic light emitting devices', Phys, Lett. A, Vol. 346, No. 1, p. 148, 2005 https://doi.org/10.1016/j.physleta.2005.07.080
  13. X. Jiang, F. L. Wong, M. K. Fung, and S. T. Lee, 'Aluminum-doped zinc oxide films as transparent conductive electrode for organic light-emitting devices', Appl. Phys. Lett., Vol. 83, No. 9, p. 1875, 2003 https://doi.org/10.1063/1.1605805
  14. T. Minami, S. Suzuki, and T. Miyata, 'Transparent conducting impurity-co-doped ZnO : Al thin films prepared by magnetron sputtering', Thin Solid Films, Vol. 398, p. 53, 2001 https://doi.org/10.1016/S0040-6090(01)01303-7
  15. 이영환, 김원종, 양재훈, 신종열, 김태완, 홍진웅, '유기발광 소자에서 유기층의 두께 및 증착속도 변화에 따른 전기적 특성', 전기전자재료학회논문지, 19권, 4호, p. 362, 2006 https://doi.org/10.4313/JKEM.2006.19.4.362
  16. 왕민성, 유인성, 박춘배, 'In-situ 분위기 Annealing에 따른 ZnO/Sapphire(0001) 박막의 구조적 특성 분석', 전기전자재료학회논문지, 19권, 8호, p. 769, 2006 https://doi.org/10.4313/JKEM.2006.19.8.769