한국안전학회지 (Journal of the Korean Society of Safety)

  • 제22권5호
  • /
  • Pages.84-89
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  • 2007
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  • 1738-3803(pISSN)
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  • 2383-9953(eISSN)
한국안전학회 (The Korean Society of Safety)
권호 표지

에스테르화합물에 대한 표준끓는점과 인화점을 이용한 폭발하한계 추산

Estimation of the Lower Explosion Limits Using the Normal Boiling Points and the Flash Points for the Ester Compounds

  • 하동명 (세명대학교 보건안전공학과)
  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University)
  • 발행 : 2007.10.31
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초록

폭발하한계는 가연성물질의 화재 및 폭발 위험성을 결정하는데 사용되는 중요한 연소특성치의 하나이다. 본 연구에서 에스테르 화합물에 대한 폭발하한계는 액체 열역학이론을 근거로 표준끓는점과 인화점을 이용하여 예측하였다. 그 결과, 문헌값과 예측값의 A.A.P.E.(average absolute percent error)는 8.80vo1%이고, A.A.D.(average absolute deviation)는 0.18vo1% 그리고 상관계수는 0.965로써 문헌값과 예측값은 일치하였다. 제시된 방법론 사용에 의해 다른 가연성물질의 폭발하한계 예측이 가능하다.

The lower explosion limit(LEL) is one of the major combustion properties used to determine the fire and explosion hazards of the combustible substances. In this study, the lower explosion limits of the ester compounds were predicted by using the normal boiling points and the flash points based on the liquid thermodynamic theory. As a results, the A.A.P.E.(average absolute percent error) and the A.A.D.(average absolute deviation) of the reported and the calculated the LEL for the ester are 8.80 vol% and 0.18 vol%, respectively and the coefficient of correlation was 0.965. From a given results, by the use of the proposed methodology, it is possible to predict the lower explosion limits of the other flammable materials.

키워드

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