Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation of Ti−TiH2−C−N2Powder by Combustion Reaction in the System of TiC0.7N0.3

Ti−TiH2−C−N2계에서 연소반응에 의한 TiC0.7N0.3 분말의 제조

  • Shin, Chang-Yun (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University) ;
  • Nersisyan, Hayk (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University) ;
  • Won, Chang-Whan (Engineering Research Center for Rapidly Solidified Materials, Chungnam National University)
  • 신창윤 (충남대학교 급속응고신소재연구소) ;
  • ;
  • 원창환 (충남대학교 급속응고신소재연구소)
  • Published : 2007.01.31
Download PDF
⟨ Previous Next ⟩

Abstract

The preparation of $TiC_{0.7}N_{0.3}$ powder by SHS in the system of $Ti-TiH_2-C$ ($N_2$ atmosphere) was investigated in this study. In the preparation of $TiC_{0.7}N_{0.3}$ powder, the effect of gas pressure, compositions such as Ti, $TiH_2$, C, and additive in mixture on the reactivity were investigated. At 50 atm of the initial inert gas pressure in reactor, the optimum composition for the preparation of pure $TiC_{0.7}N_{0.3}$ was $0.75Ti+0.25TiH_2+0.7C+0.5NaCl$. The $TiC_{0.7}N_{0.3}$ powder synthesized in this condition was a single phase with irregular shape.

Keywords

References

  1. Z. Shanyong, 'Titanium Carbonitride-Based Cermets: Processes and Properties,' Mater. Sci. Eng., A, 163 141-148 (1993) https://doi.org/10.1016/0921-5093(93)90588-6
  2. O. Knotek, F. Loffler, and G. Kramer, 'Multicomponent and Multilayer Physically Vapour Deposited Coatings for Cutting Tools,' Surf. Coat. Technol., 54-55 [16] 241-248 (1992) https://doi.org/10.1016/S0257-8972(09)90057-3
  3. A. G. Merzhanov, A. M. Stolin, and V. V. Podlesov, 'SHS Extrusion of Long Size Articles from Metalloceramic Materials,' J. Eur. Chem. Soc., 17 [2-3] 447-451 (1997) https://doi.org/10.1016/S0955-2219(96)00208-7
  4. A. G. Merzhanov, 'History and Recent Development in SHS,' Intern., 21 [5] 371-379 (1995) https://doi.org/10.1016/0272-8842(95)96211-7
  5. J. Kiser and R. M. Spriggs, 'Soviet SHS Technology : A Potential U. S. Advantage in Ceramics,' Ceram. Bull., 68 [6] 1165-1167 (1989)
  6. M. H. Ryu, J. H. Lee, C. W. Won, and H. Nersisyan, 'Synthesis and Characteristics of $LiCoO_2$ Powders Prepared by SHS Process(in Korean),' J. Kor. Ceram. Soc., 41 [5] 388- 394 (2004) https://doi.org/10.4191/KCERS.2004.41.5.388
  7. I. H. Song, J. Y. Yun, and H. D. Kim, 'Fabrication of Porous $MoSi_2$ Material for Heating Element through Self-Propagating High Temperature Synthesis Process(in Korean),' J. Kor. Ceram. Soc., 41 [1] 62-68 (2004) https://doi.org/10.4191/KCERS.2004.41.1.062
  8. K. R. Han, D. I. Kang, and C. S. Kim, 'Preparation of $B_4CAl_2O_3$ Composite Powder by Self-Propagation High-Temperature Synthesis(SHS) Process Under High Pressure(in Korean),' J. Kor. Ceram. Soc., 40 [1] 18-23 (2003) https://doi.org/10.4191/KCERS.2003.40.1.018
  9. K. S. Yun, J. H. Lee, H. Nersisyan, C. W. Won, and H. S. Jung, 'Preparation of ${\alpha}-Si_3N_4$ Powder in Reaction System Containing Molten Salt by SHS-Part 1. Synthesis of Powder( in Korean),' J. Kor. Ceram. Soc., 41 [3] 235-242 (2004) https://doi.org/10.4191/KCERS.2004.41.3.235
  10. H. Ha, G.-M. Hwang, and H.-C. Lee, 'A Study on the Synthesis of Titanium Carbonitride by SHS(Self-Propagating Hih-Temperaure Synthesis) Method(in Korean),' J. Kor. Ceram. Soc., 31 [6] 637-42 (1994)