Surface Modification of Polymethyl methacrylate(PMMA) by Laser Surface Treatment for Microfluidic Chip

유체소자 성능향상을 위한 Polymethyl methacrylate(PMMA)의 레이저 표면처리

  • 신성권 (인하대학 전기공학과) ;
  • 이상돈 (국립대학 전기공학과) ;
  • 이천 (인하대학 전기공학과)
  • Published : 2007.02.01

Abstract

After the advent of micro-Total Analysis Systems(${\mu}-TAS$) based on silicon various polymer for microfluidic chip has been studied. Polymer materials for microfluidic compared with silicon and glass which were traditional materials of a microfluidic chip, have the advantages of economical efficiency simple manufacturing process and wide materials selectivity corresponding to fluids. Surface energy of polymers we, however lower than silicon or glass. To overcome this problem, various surface modification methods have been investigated. The surface modification using laser has the advantage of the simple experiment that only directly irradiated laser beam on the material surface in the air. This work discuss the surface modification of polymethly methacrylate(PMMA) by 4th harmonic Nd:YAG laser (${\lambda}266nm$, pulse) treatment. After the laser treatment, the PMMA surface was investigated using a contact angle measuring instrument. The contact angle was decreased with a increase of the surface oxygen content. This result means the surface energy of PMMA was increased by the laser treatment without changing of its bulk characteristics.

Keywords

References

  1. A. Manz, N. Graber and H. M. Widmer, 'Miniaturized total chemical analysis systems: A novel concept for chemical sensing.', Sensors and Actuators B, Vol. 1, p. 244, 1990
  2. R. E. Oosterbroek and A. van den Berg, 'Lab-on-achip', Elsevier, p. 65, 2000
  3. E. M. Liston, L. Martinu, and M.R. Wertheimer, 'Plasma surface modification of polymers for improved adhesion: A critical review', J. Adhesion Sci. Technol., Vol 7, p. 1091, 1993
  4. J. A. Folkes, 'Developments in laser surface modificaion and coating', Surface Coation Technol.,Vol 63, p. 65, 1994
  5. C. Lee, D. Y. Kim, J. H. Kim, K. C. Lee, and C. S. Hui, 'Surface modification of silicon by laser surface treatment: Improvement of adhesion and copper deposition.' Journal of electronic materials, Vol. 34, No.2, p. 132, 2005 https://doi.org/10.1007/s11664-005-0223-1
  6. S. K. Shin, C. Lee, 'Surface modification of polydimethylsiloxane using Nd:YAG laser', KIEEME, Vol. 19, No.2, p. 181, 2006 https://doi.org/10.4313/JKEM.2006.19.2.181
  7. R. Srinivasan and B. Braren, 'Lasers in polymer science and technology: Applications', CRC press, Vol 3, p. 164
  8. P. Laurens, M. OuId Bouali, F. Meducin, and B. Sadras, 'Characterization of polymer surfaces after excimer laser treatments below the ablation threshold', Applied Surface Science, Vol. 154, p. 211, 2000
  9. J. y. Cheng, C. W. Wei, K. H. Hsu and T. H. Young, 'Direct-write laser micromachining and universal surface modification of PMMA for device development', Sensors and Actuators B, Vol. 99, p. 186, 2004 https://doi.org/10.1016/j.snb.2003.10.022