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Piezoelectric and Dielectric Characteristics of Lead Free [Li0.04(NayK1-y)0.96](Nb0.86Ta0.1Sb0.04)O3 Ceramics with the Variations of Na/K Ratio

Na/K 비 변화에 따른 무연 [Li0.04(NayK1-y)0.96](Nb0.86Ta0.1Sb0.04)O3 세라믹스의 압전 및 유전특성

  • 이갑수 (세명대학교 전기공학과) ;
  • 류주현 (세명대학교 전기공학과) ;
  • 홍재일 (동서울대학 전기정보제어과) ;
  • 이석태 (세명대학교 전자공학과) ;
  • 김용운 (세경대학 소방안전관리과) ;
  • 정회승 (주성대학 의용전자기기연구소)
  • Published : 2007.01.01

Abstract

In this paper, lead-free [$Li_{0.04}(Na_{y}K_{1-y})_{0.96}](Nb_{0.86}Ta_{0.1}Sb_{0.04})O_{3}$ (y=0.4 - 0.58) ceramics were manufactured using conventional miked oxide method for acoustic emission(AE) sensor application and their dielectric and piezoelectric properties were investigated with the variations of Na/K ratio. The samples in the composition Na/K=54/46 exhibited excellent electrical properties of $d_{33}=300$ PC/N and kp=0.49. Taking into consideration above piezoelectric properties, it can be concluded that the [$Li_{0.04}(Na_{y}K_{1-y})_{0.96}](Nb_{0.86}Ta_{0.1}Sb_{0.04})O_{3}$ system ceramics are the promising lead-free materials capable of substituting PZT system ceramics.

Keywords

References

  1. J. W. Waanders: Piezoelectric Ceramics-properties and Application, Philios Components, Eindhoven, 1991
  2. B. Jaffe, W. R. Cook, and H. Jaffe: Piezoelectric Ceramics, Academic. New York, 1971
  3. 이미영, 류성림, 류주현, 정광현, 정영호, 홍재일, 윤현상, '$MnO_{2}$ 첨가에 따른 무연 Bi(Na,K)TiO-$SrTiO_{3}$ 세라믹스의 유전 및 압전 특성', 전기전자재료학회논문지, 17권, 10호, p. 1056, 2004
  4. J. H. Yoo, J. I. Hong, H. S. Lee, Y. H. Jeong, B. Y. Lee, H. S. Song, and J. S. Kwon, 'Piezoelectric and dielectric properties of $Na_{2}O_{3}$ added Bi(Na,K)TiO-$SrTiO_{3}$ ceramics for pressure sensor application', Sensors and Actuators A: Physical, Vol. 126, Iss. 1, p. 41, 2006 https://doi.org/10.1016/j.sna.2005.09.005
  5. Y. Guo, K.-I. Kakimoto, and H. Ohsato, 'Dielectric and piezoelectric properties of lead-free $(Na_{0.5}K_{0.5})NbO_{3}$-$SrTiO_{3}$ ceramics', Solid State Commnications 129, p. 279, 2004 https://doi.org/10.1016/j.ssc.2003.10.026
  6. H. Nagata and T. Takenaka, 'Additive effects on electrical properties of ($Bi_{1/2}Na_{1/2}$) $TiO_3$ ferroelectric ceramics', J. Euro. Ceram. Soc., Vol. 21, p. 1299, 2001 https://doi.org/10.1016/S0955-2219(01)00005-X
  7. A. Sasaki, T. Chiba, Y. Mamiya, and E. Otsuki, 'Dielectric and piezoelectric properties of $(Bi_{0.5}Na_{0.5})TiO_{3}$-$Bi_{0.5}K_{0.5}$ $TiO_3$ systems', Jpn. J. Appl. Phy., Vol. 38, No. 9B, p. 5564, 1999 https://doi.org/10.1143/JJAP.38.5564