Environmental Analysis Health and Toxicology

The Korean Society of Environmental Health and Toxicology (환경독성보건학회)
권호 표지

Distribution between Air-Soil Concentration of Organochlorine Pesticides

유기염소계 살충제의 대기-토양간 분배

  • Choi, Min-Kyu (Marine Environment Research Team, National Fisheries Research & Development Institute) ;
  • Chun, Man-Young (Department of Environmental Engineering, National Hankyoung University)
  • Published : 2007.12.31
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Abstract

This paper was studied to investigate the equilibrium state between organochlorine pesticides (OCPs) concentration of air and soil, and to know whether soil is a secondary pollution source of OCPs in air or not. The OCPs concentration of air ($C_{air}$) and soil ($C_{soil}$) is not related to molecular weight, vapor pressure ($P_L$) and octanol-air partition coefficient ($K_{oa}$). The slope of the regression line between soil-air partition coefficient ($K_{sa}$) and scavenging coefficient ($C_{soil}/C_{air}$) was 0.2952, which the OCPs concentration between air and soil did not reached to the equilibrium state. The soil/air fugacity quotients ($f_{soil}/f_{air}$) of p, p'-DDT/DDD/DDE and ${\beta}-HCH\;(0.30{\sim}0.67$), which is smaller than 1, means the deposit of OCPs from air to soil. However, $f_{soil}/f_{air}$ of heptachlor, heptachlor epoxide, ${\alpha}/{\gamma}-chlordane$, trans-nonachlor, endosulfan sulfate and ${\alpha}/{\gamma}-HCH\;(1.90{\sim}73.25)$, which is greater than 1, means that soil is secondary pollution source of OCPs in air.

Keywords

References

  1. 정예표, 최민규, 여현구, 천만영, 대기중 난분해성 유기염소계 농약의 계절별 농도변화, 한국환경농학회지 2001; 20(2): 79-85
  2. 최민규, 여현구, 김태욱, 천만영, 선우영. 교외지역에서 대기중 Hexachlorocyclohexane의 농도분포 및 온도의존성, 한국대기환경학회지 2002a; 18(3): 183-192
  3. 최민규, 여현구, 김태욱, 천만영, 선우영. 교외지역에서 대기중 유기염소계 살충제의 농도분포, 대한환경공학회지 2002c; 24(6): 1091-1103
  4. 최민규, 여현구, 천만영, 선우영. 도시 대기 중 유기염소계 살충제의 농도수준 및 배출 특성, 한국대기환경학회지 2002b; 18(4):275-284
  5. 최민규, 천만영. 대기 중에서 가스상 유기염소계 농약의 농도변화 패턴, 한국환경독성학회지 2007a; 22(2): 111-118
  6. 최민규, 천만영. 대기 중에서 가스상 유기염소계 살충제의 반감기, 한국환경독성학회지 2007b; 22(2): 177-184
  7. 한기학, 박창규, 김복영, 김재정, 이규승, 이영환, 신제성, 엄기태, 정영상, 허종수. 농업환경화학, 동화기술 1996; 216-282
  8. Bidleman TF and Leone AD. Soil-air exchange of organochlorine pesticides in the Southern United States, Environmental Pollution 2004; 128: 49-57 https://doi.org/10.1016/j.envpol.2003.08.034
  9. Cousins I and Jones KC. Air-soil exchange of semi-volatile organic compounds (SOCs) in the UK, Environmental Pollution 1998; 102: 105-118 https://doi.org/10.1016/S0269-7491(98)00069-4
  10. Duarte-Davidson R, Sewart A, Alcok RE, Cousins IT and Jones KC. Exploring the balance between sources, deposition, and the environmental Burden of PCDD/Fs in the U.K., terrestrial environment: an aid to identifying uncertainties and research needs, Environ Sci Technol 1997; 31: 1-11 https://doi.org/10.1021/es960121s
  11. Finizio A, Bidleman TF and Szeto SY. Emission of chiral pesticides from an agricultural soil in the fraser valley, British Columbia, Chemosphere 1998; 36(2): 345-355 https://doi.org/10.1016/S0045-6535(97)00272-5
  12. Harner T, Wideman JL, Jantuen LMM, Bidleman TF and Parkhurst WJ. Residues of organochlorine pesticides in Alabama soils, Environmental Pollution 1999; 106: 323-332 https://doi.org/10.1016/S0269-7491(99)00110-4
  13. Harrad SJ, Sewart A, Alcock RE, Boumphrey R, Burnett V, Duarte-Davidson R, Halsall C, Sanders G, Waterhouse K, Wild SR and Jones KC. Polychlorinated biphenyls (PCBs) in the british environment: sinks, sources and temporal trends, Environmental Pollution 1994; 85: 131-146 https://doi.org/10.1016/0269-7491(94)90079-5
  14. Hyungu Y, Minkyu C, Manyoung C and Young SW. Airsoil partitioning of PCBs in rural area, J of Korean Society for Atmospheric Evironment 2003; 19(E1): 1-9
  15. Karickhoff SW. Semi-permeable estimation of sorption of hydrophobic pollutants on natural sediments and soils, Chemosphere 1981; 10: 833-849 https://doi.org/10.1016/0045-6535(81)90083-7
  16. Kim JH and Alistair S. Distribution of organochlorine pesticides in soils from South Korea, Chemosphere 2001; 43: 137-140 https://doi.org/10.1016/S0045-6535(00)00281-2
  17. Lee GM, Robert, BV, Harner T and Jones CK. Short-term temperature-dedependent air-surface exchange and atmospheric concentrations of polychlorinated naphthalenes and organochlorine pesticides, Environ Sci Technol 2000; 34: 393-398 https://doi.org/10.1021/es9907414
  18. Mackay D. Multi-media environmental models: the fugacity approach, Lewis Publishers, 1991; Chelsea
  19. Mackay D, Shiu WYand Ma KC. Illustrated Handbook of Physical-Chemical Properies and Environmental Fate for Organic Chemicals, Volume V, Lewis publishers 1997
  20. McConnell LL, Kucklick JR, Bidleman TF, Ivanov GP and Chemyak SM. Air-water gas exchange of organochlorine compounds in Lake Baikal, Russia, Environ Sci Technol 1996;30: 2975-2983 https://doi.org/10.1021/es9509487
  21. McLachlan MS. Bioaccumulation of hydrophobic chemicals in agricultural food chains, Environ Sci Technol 1996; 30: 252-259 https://doi.org/10.1021/es9502738
  22. McLachlan MS. A simple model to predict the accumulation of PCDD/Fs in an agricultural food chain, Chemosphere 1997; 34: 1263-1276 https://doi.org/10.1016/S0045-6535(97)00424-4
  23. Shoeib M and Harner T. Using measured octanol-air partition coefficients to explain environmental partitioning of organchlorine pesticides, Environmental Toxicology and Chemistry 2002; 21(5): 984-990 https://doi.org/10.1897/1551-5028(2002)021<0984:UMOAPC>2.0.CO;2