Journal of the Mineralogical Society of Korea (한국광물학회지)

The Mineralogical Society of Korea (한국광물학회)
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Compression Study of Goethite at Room Temperature

상온에서 괴타이트에 대한 압축 연구

  • Kim, Y.H. (Department of Earth and Environment Science and Basic Science Research Institute, Gyeongsang National University) ;
  • Hwang, G.C. (Department of Earth and Environment Science and Basic Science Research Institute, Gyeongsang National University) ;
  • Do, J.K. (Department of Earth and Environment Science and Basic Science Research Institute, Gyeongsang National University)
  • 김영호 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 황길찬 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 도재기 (경상대학교 지구환경과학과 및 기초과학연구소)
  • Published : 2007.12.30
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Abstract

A natural FeOOH-goethite was compressed up to 9.5 GPa at room temperature using a DIA-type large volume apparatus with synchrotron radiation. Energy dispersive x-ray diffraction method was employed to measure its compressibility and NaCl was used for high pressure determinations. Bulk modulus was determined to be 131.1 (${\pm}5.8$) GPa by the Birch-Murnaghan equation of state with $K_0'$ fixed to 4. The present result is not in accord with the previous measurements, which vary from 111 to 147.9 GPa.

천연시료 FeOOH-괴타이트에 대한 압축성을 측정하기 위하여 방사광과 라지 발륨 기기를 이용하여 상온에서 압축실험을 시행하였다. 에너지분산 x-선 회절법을 적용하였고 압력은 NaCl을 이용하여 측정하였다. 버치-머내한 상태방정식을 이용하여 계산된 체적탄성률은 131.1(5.8) GPa이었고 이때 $K_0'$은 고정된 값 4를 이용하였다. 현재 측정된 간은 이전에 발표된 값($111{\sim}147.9GPa$)과 일치하지 않고 차이를 보이고 있다.

Keywords

References

  1. Chen J., Parise J.B., Li R., Weidner D.J. and Vaughn M. (1998) The imaging plate system interfaced to the large volume press at beamline X-17B1 of the National Synchrotron Light Source, Properties of Earth and Planetary Materials at High Pressure and Temperature (eds., M.H. Manghnani and T. Yagi), Geophys. Mono. 101, AGU, 139-144
  2. Decker D.L. (1971) High pressure equation of state of NaCl, KCl and CsCl, J. Appl. Phys., 42, 3239-3247 https://doi.org/10.1063/1.1660714
  3. Duffy T.S., Ahrens T.J. and Lange M.A. (1991) Shock wave equation of state of brucite $Mg(OH)_{2}$. J. Geophys. Res., 96, 14319-14330 https://doi.org/10.1029/91JB00987
  4. Fei Y. and Mao H.K. (1993) Static compression of $Mg(OH)_{2}$ to 78 GPa at high temperature and constraints on the equation of state of fluid $H_{2}O$, J. Geophys. Res., 98(B7), 11875-11884 https://doi.org/10.1029/93JB00701
  5. Grevel K.D., Burchard M., Fasshauer D.W. and Peun T. (2000) Pressure-volume-temperature behavior of diaspore and corundum: An in situ x-ray diffraction study comparing different pressure media, J. Geophys. Res., 105, 27877-27887 https://doi.org/10.1029/2000JB900323
  6. Haines J., Leger J.M., Gorelli F., Klug D.D., Tse J.S. and Li Q. (2001) X-ray diffraction and theoretical studies of the high-pressure structures and phase transitions in magnesium fluoride, Phys. Rev. B, 64, 134110-10 https://doi.org/10.1103/PhysRevB.64.134110
  7. Kim Y.H. and Yi Z. (1997) High pressure x-ray diffraction study on a goethite using synchrotron radiation, J. Miner. Soc., Korea, 10, 75-81
  8. Liu L. (1987) Effects of $H_{2}O$ on the phase behavior of the forsterite-enstatite system at high pressures and temperatures and implications for the Earth, Phys. Earth Planet. Inter., 49, 142-167 https://doi.org/10.1016/0031-9201(87)90138-5
  9. Mao H.K., Shu J. Hu J. and Hemley R.J. (1994) High pressure x-ray diffraction study of diaspore, Solid State Comm., 90(8), 497-500 https://doi.org/10.1016/0038-1098(94)90053-1
  10. Meade C. and Jeanloz R. (1990) Static compression of $Ca(OH)_{2}$ at room temperature: Observations of amorphization and equation of state measurements to 10.7 GPa, Geophys. Res. Lett., 17, 1157-1160 https://doi.org/10.1029/GL017i008p01157
  11. Nagai T., Kagi H. and Yamanaka T. (2003) Variation of hydrogen bonded OO distances in goethite at high pressure, Am. Mineral., 88, 1423-1427 https://doi.org/10.2138/am-2003-1005
  12. Piermarini G.J., Block S. and Barnett J.D. (1973) Hydrostatic limits in liquids and solids to 100 kbar, J. Appl. Phys., 44, 5377-5380 https://doi.org/10.1063/1.1662159
  13. Ruoff A.L. and Vanderborgh C.A. (1993) Hydrogen reduction of ruby at high pressure: Implication for claims of metallic hydrogen, Phys. Res. Lett., 71, 4279
  14. Ringwood A.E. and Major A. (1967) High pressure reconnaissance investigation in the system $Mg_{2}SiO_{4}$- MgO-$H_{2}O$ , Earth Planet. Sci. Lett., 2, 130-133 https://doi.org/10.1016/0012-821X(67)90114-8
  15. Sato Y. and Akimoto S.I. (1979) Hydrostatic compression of four corundum-type compounds:$\alpha$- $Al_{2}O_{3}$, $V_{2}O_{3}$, $Cr_{2}O_{3}$, and $\alpha$-$Fe_{2}O_{3}$, J. Appl. Phys., 50(8), 5285-5291 https://doi.org/10.1063/1.326625
  16. Tyburczy J.A., Duffy T.S. Ahrens T.J. and Lange M.A. (1991) Shock wave equation of state of serpentine to 150 GPa: implications for the occurrence of water in the Earth's lower mantle, J. Geophys. Res., 96, 18011-18027 https://doi.org/10.1029/91JB01573
  17. Utsumi W., Weidner D.J. and Libermann R. (1998) Volume measurement of MgO at high pressures and high temperatures, Properties of Earth and Planetary Materials at High Pressure and Temperature (Eds. M.H. Manghnani and T. Yagi), Geophys. Mono., 101, AGU, 327-333
  18. Wang Y., Weidner D.J. and Meng Y. (1998) Advances in equation-of-state measurements in SAM-85, Properties of Earth and Planetary Materials at High Pressure and Temperature (Eds. M.H. Manghnani and T. Yagi), Geophys. Mono., 101, AGU, 365-372
  19. Williams Q. and Guenther L. (1996) Pressure-induced changes in the bonding and orientation of hydrogen in FeOOH-goethite, Sol. Stat. Comm., 100(2), 105-109 https://doi.org/10.1016/0038-1098(96)00374-2
  20. Winkler B., Hytha M., Pickard C., Milman V., Warren M. and Segall M. (2001) Theoretical investigation of bonding in diaspore, Eur. J. Mineral., 13, 343-349 https://doi.org/10.1127/0935-1221/01/0013-0343
  21. Xu J.A., Hu J., Ming L.C. and Huang E. and Xie H. (1994) The compression of diaspore, AlO(OH) at room temperature up to 27 GPa, Geophys. Res. Lett., 21, 161-164 https://doi.org/10.1029/94GL00026
  22. Zhang J. (2000) Effect of pressure on the thermal expansion of MgO up to 8.2 GPa, Phys. Chem. Minerals, 27, 145-148 https://doi.org/10.1007/s002690050001