Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation of Red Perylene Fluoroionophore Containing Calix[4]azacrown Ether and Their Ionophoric Properties

  • Jeon, Young-Min (Department of Chemistry and Institute of Basic Sciences, Dankook University) ;
  • Lim, Tae-Ho (Department of Chemistry and Institute of Basic Sciences, Dankook University) ;
  • Kim, Jong-Gyu (Department of Chemistry and Institute of Basic Sciences, Dankook University) ;
  • Kim, Jong-Seung (Department of Chemistry, Dankook University) ;
  • Gong, Myoung-Seon (Department of Chemistry and Institute of Basic Sciences, Dankook University)
  • Published : 2007.05.20
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Abstract

Novel new red-light emitting perylene fluoroionophore N,N'-dipropyl-1,7-bis(calix[4]azacrown-5-crown-5)- 3,4,9,10-perylene tetracarboxy diimide (3) was prepared by reacting N,N'-dipropyl-1,7-dibromo-3,4,9,10- perylene tetracarboxy diimide (1) with calix[4]azacrown-5-crown-5. Also the alternating copolymer (4) with similar repeating unit was prepared reacting by calix[4]bisazacrown-5 with 1. Metal ion binding by 3 and 4 leads to a blue-shift of absorption band and emission spectra. When ionophoric characteristics were investigated by binding alkali, alkali earth metal and various metal ions, polymeric ionophores displayed large fluorescence decreasing effects with K+, Ag+ and Ba2+, which was rationalized by photo-induced charge transfer (PCT).

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References

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