Bulletin of the Korean Chemical Society

  • 제28권11호
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  • Pages.2025-2028
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  • 2007
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Polymer-supported Zinc Tetrahalide Catalysts for the Coupling Reactions of CO2 and Epoxides

  • Lee, Bo-Ra (Department of Chemistry, Kyung Hee University) ;
  • Ko, Nan-Hee (Department of Chemistry, Kyung Hee University) ;
  • Ahn, Byoung-Sung (Environment and Process Division, Korea Institute of Science and Technology) ;
  • Cheong, Min-Serk (Department of Chemistry, Kyung Hee University) ;
  • Kim, Hoon-Sik (Department of Chemistry, Kyung Hee University) ;
  • Lee, Je-Seung (Department of Chemistry, Kyung Hee University)
  • 발행 : 2007.11.20
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초록

Homogeneous zinc tetrahalide complexes, highly active catalysts for the coupling reactions of alkylene oxide and CO2 produce alkylene carbonates, were heterogenized due to their tendency to decompose produced alkylene carbonates during the distillation process. Heterogenization of homogeneous zinc tetrahalide complexes was achieved by polymerizing 1-alkyl-3-vinylimidazolium zinc tetrahalides. These polymerized zinc tetrahalide catalysts displayed similar activities to their corresponding monomeric analogues for the coupling reactions of carbon dioxide with ethylene oxide (EO) or propylene oxide (PO) to produce ethylene carbonate (EC) or propylene carbonate (PC). TGA studies showed that the polymer-supported zinc tetrahalide catalysts are thermally stable up to 320 oC. The catalyst recycle test showed that the supported catalysts could be reused over six times. After removal of the polymer-supported catalyst through a simple filtration, EC was able to be isolated without decomposition.

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  2. The Use of Supported Acidic Ionic Liquids in Organic Synthesis vol.19, pp.7, 2014, https://doi.org/10.3390/molecules19078840
  3. Acidic Ionic Liquids vol.116, pp.10, 2016, https://doi.org/10.1021/acs.chemrev.5b00763
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  5. vol.38, pp.2, 2017, https://doi.org/10.1002/bkcs.11068
  6. Investigation of Prins reaction for the synthesis of 2, 4- disubstituted tetrahydropyran derivatives and 1, 3-dioxanes using polyaniline supported acid as reusable catalyst vol.123, pp.5, 2011, https://doi.org/10.1007/s12039-011-0122-3
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  8. Reusable and efficient polymer-supported task-specific ionic liquid catalyst for cycloaddition of epoxide with CO2 vol.148, pp.3, 2007, https://doi.org/10.1016/j.cattod.2009.07.070